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dc.creatorAngell, C. L.en_US
dc.date.accessioned2006-06-15T12:46:48Z
dc.date.available2006-06-15T12:46:48Z
dc.date.issued1956en_US
dc.identifier1956-C-10en_US
dc.identifier.urihttp://hdl.handle.net/1811/7465
dc.description$^{1}$This work was carried out at the University of Cambridge, England during the tenure of an Oliver Gatty Studentship. 1C. J. Brown, Acta Cryst. 7:92 (1954)""en_US
dc.descriptionAuthor Institution: The Harrison M. Randall Laboratory of Physics, University of Michiganen_US
dc.description.abstractThe infrared spectra of ethylene carbonate $(CH_{2}-O-CO-O-CH_{2}$ in the solid, liquid and vapor states and its solutions in water, chloroform, benzene, carbon tetracloride and carbon disulfide have been studied between 3600 and $400 cm^{-1}$, together with the Raman spectrum in aqueous solution. Previous X-ray crystal structure $determination^{1}$ has shown that the five-membered ring of the ethylene carbonate molecule is not planar and has symmetry $C_{2}$ in the crystal. Evidence will be presented from the spectroscopic work that the symmetry of the molecule changes from $C_{2}$ in the solid state to $C_{2{v}}$ in the other states and that the five-membered ring becomes planat. An assignment of all the observed absorption bands will be given in terms of the fundamental vibrations of the molecule.en_US
dc.format.extent93009 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoenen_US
dc.publisherOhio State Universityen_US
dc.titleTHE INFRARED SPECTRA AND STRUCTURE OF ETHYLENE $CARBONATE^{\#}$en_US
dc.typearticleen_US


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