dc.creator Decius, J. C. en_US dc.date.accessioned 2006-06-15T12:45:27Z dc.date.available 2006-06-15T12:45:27Z dc.date.issued 1955 en_US dc.identifier 1955-K-2 en_US dc.identifier.uri http://hdl.handle.net/1811/7400 dc.description Author Institution: Department of Chemistry, Oregon State College en_US dc.description.abstract Varitation of the $C^{12} - C^{13}$ ratio in carbonates of the aragonite lattice leads to fine structure in the 12$\mu$ region whose spacing and qualitative intensity can be fitted satisfactorily by the introduction of a nearest neighbor coupling constant in the potential energy. The coupling constant is believed to arise from dipole-dipole forces. From the coupling constant the value of the CO bond moment is found to be $1.52 \pm 0.1$ debyes in $BaCO_{3}$, $1.56 \pm 0.1$ debyes in $SrCO_{3}$. The coupling is so large in $CaCO_{3}$ (on account of the inverse cube dependence upon interdipole distance) that the perturbation theory cannot be applied without modification. en_US dc.format.extent 66652 bytes dc.format.mimetype image/jpeg dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title CO BOND MOMENT IN THE CARBONATE ION en_US dc.type article en_US
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