THE MICROWAVE SPECTRUM OF TRIFLUORONITROMETHANE
Publisher:
Ohio State UniversityAbstract:
Several series of $\Delta J = + 1$ transitions have been observed in the rotational spectrum of $CF_{3}NO_{2}$. The spectrum has the same qualitative features as that of $CH_{3}NO_{2}$, but is more complicated. Because the moment of inertia of the $CF_{3}$ group is large, many internal rotation states are populated. In addition, the low asymmetry of the molecule results in a close spacing of the lines over a relatively narrow frequency range so that the Stark effect of most lines is not resolvable and many of the lines themselves cannot be resolved. A number of lines have, however, been assigned and the rotational constants $A(NO_{2})$, B, and C have been determined. The barrier to internal rotation will be evaluated.
Description:
Author Institution: Department of Chemistry and Chemical Engineering, University of California
Type:
articleOther Identifiers:
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