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dc.creatorAllen, Harry C., Jr.en_US
dc.creatorNaylor, Robert E.en_US
dc.creatorPlyler, Earle K.en_US
dc.descriptionAuthor Institution: Department of Physics, Michigan State College; Mallinckrodt Chemical Laboratories, Harvard University; Mallinckrodt Chemical Laboratories, National Bureau of Standardsen_US
dc.description.abstractThe absorption of deuterium sulfide has been observed and measured under high resolution from 4500 to $4675 cm^{-1}$. The rotational structure has been analyzed through the use of published energy and line strength tables for the rigid asymmetric rotor. A classical centrifugal distortion was applied to the rigid energy levels. The absorption is attributed to the vibrational band having an excited state with the quantum numbers $(n_{1}, n_{2}, n_{3}) = (1, 1, 1)$. More than 100 lines with $J<8$ have been assigned with an average deviation of less than $.08 cm^{-1}$. Using the ground state inertial constants the D-S distance is calculated to be 1.345A and the DSD angle to be $92^{\circ}16^{\prime}$, in excellent agreement with similar structural parameters determined for $H_{2} S$ from infrared studies.en_US
dc.format.extent91009 bytes
dc.publisherOhio State Universityen_US
dc.titleTHE DEUTERIUM SULFIDE BAND AT $4590 cm^{-1}$en_US

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