dc.creator Allen, Harry C., Jr. en_US dc.creator Naylor, Robert E. en_US dc.creator Plyler, Earle K. en_US dc.date.accessioned 2006-06-15T12:43:57Z dc.date.available 2006-06-15T12:43:57Z dc.date.issued 1954 en_US dc.identifier 1954-R-3 en_US dc.identifier.uri http://hdl.handle.net/1811/7329 dc.description Author Institution: Department of Physics, Michigan State College; Mallinckrodt Chemical Laboratories, Harvard University; Mallinckrodt Chemical Laboratories, National Bureau of Standards en_US dc.description.abstract The absorption of deuterium sulfide has been observed and measured under high resolution from 4500 to $4675 cm^{-1}$. The rotational structure has been analyzed through the use of published energy and line strength tables for the rigid asymmetric rotor. A classical centrifugal distortion was applied to the rigid energy levels. The absorption is attributed to the vibrational band having an excited state with the quantum numbers $(n_{1}, n_{2}, n_{3}) = (1, 1, 1)$. More than 100 lines with $J<8$ have been assigned with an average deviation of less than $.08 cm^{-1}$. Using the ground state inertial constants the D-S distance is calculated to be 1.345A and the DSD angle to be $92^{\circ}16^{\prime}$, in excellent agreement with similar structural parameters determined for $H_{2} S$ from infrared studies. en_US dc.format.extent 91009 bytes dc.format.mimetype image/jpeg dc.language.iso en en_US dc.publisher Ohio State University en_US dc.title THE DEUTERIUM SULFIDE BAND AT $4590 cm^{-1}$ en_US dc.type article en_US
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