THE INFRARED SPECTRA OF THIN FILMS OF SIX $HEXAFLUORIDES^{*}$
Publisher:
Ohio State UniversityAbstract:
The infrared spectra of thin films of the hexafluorides of sulfur, selenium, tellurium, molybdenum, tungsten, and uranium have been observed from 2 to 15$\mu$. For $UF_{6}$, the observations were extended to 18$\mu$ in order to observe $\sigma_{3}$. The films were deposited on a silver chloride plate chilled by heat conduction through a hollow silver mounting bracket containing liquid nitrogen. $\sigma_{3}$ was found to fall at longer wavelengths in the solid state than in the gas state for all six molecules. $\sigma_{1}+\sigma_{3}$ and $\sigma_{2}+\sigma_{3}$ were observed doubled in the solid state in each case.
Description:
$^{*}$This document is based on work performed for the Atomic Energy Commission by Carbide and Carbon Chemicals Company, a division of Union Carbide and Carbon Corporation, at Oak Ridge, Tennessee.
Author Institution: K-25 Technical Division, Carbide and Carbon Chemicals Company
Author Institution: K-25 Technical Division, Carbide and Carbon Chemicals Company
Type:
articleOther Identifiers:
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