Browsing Abstracts of OSU International Symposium on Molecular Spectroscopy 1990-1999 by Title
Now showing results 2866-2885 of 3912
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RAD-3 SUBMILLIMETER-WAVE SEPECTRUM OF ACETALDEHYDE
Belov, Sergey P.; Tretyakov, M. Yu.; Hougen, Jon T.; Kleiner, I. ( 1992 )A broad-band room-temperature submillimeter wave spectrum containing approximately 5000 lines of $CH_{3}CHO$ in the region from 165 to 417 GHz has been recorded with the RAD-3 $spectrometer^{1}$in Nizhni Novgorod (formerly ... -
THE RADIAL HAMILTONIAN OPERATOR OF $HeH^{+}$
Coxon, John A.; Hajigeorgiou, P. G. ( 1993 )Experimental line positions for $^{3}HeH^{+}, ^{4}HeH^{+}, ^{3}HeD^{+}$, and $^{4}HeD^{+}$ have been employed in the determination of an effective non-adiabatic radial Hamiltonian operator for the ground $X^{1}\Sigma^{+}$ ... -
RADIATILVE AND NONRADIATIVE DECAY OF ELECTRONICALLY EXCITED NCO
Wright, Scott A.; Dagdigian, Paul J. ( 1996 )Electronically excited levels in the NCO free radical have been probed using laser fluorescence excitation, in order to observe higher vibronic levels of the $\tilde{A}^{2}\Sigma^{+}$ state and to locate the onset of ... -
Radiative Transition Probabilities for all Vibrational Levels in the $X^{1}\sum ^{+}$ State of HF
Zemke, W. T.; Stwalley, W. C.; Langhoff, S. R.; Valderrama, G. L.; Berry, Michael J. ( 1991 )With the complete potential energy curve and dipole moment function at all internuclear distances R, the calculation of dipole moment matrix elements is possible for any vibration-rotation transition desired. we use an ... -
RADIO FREQUENCY-INFRARED DOUBLE RESONANCE MEASUREMENT OF THE ELECTRIC DIPOLE MOMENT IN BEND-STRETCH COMBINATION VIBRATIONAL STATES OF HCCD
Marshall, Mark D.; Izgi, Kamil Can; Muenter, J. S. ( 1996 )With a small permanent electric dipole moment due to differences in zero point motion between hydrogen and deuterium, monodeuteroacetylence, HCCD, is particularly well-suited for studying changes in the dipole moment upon ... -
Radiofrequency/optical double resonance spactroscopy of $HO_{2}$.
Noerregaard, Anne; Hazell, Irene; Bjerre, Nis ( 1994 )Using a Ti-sapphire laser and a radiofrequency wave guide in combination with a fast, mass-selected beam of $He_{2}$ in the meta-stable a ${^{3}}\Sigma_{u}{^{+}}$ state, we have measured the fine structure splittings in ... -
RAMAN AND FAR INFRARED SPECTRA, CONFORMATIONAL STABLITY, BARRIERS TO INTERNAL ROTATION, AND AB INITIO CALCULATIONS OF ALLYL CYANIDE
Drew, A . S.; Durig, J. R. ( 1993 )The Raman (3200 to $10 cm^{-1}$) spectra of allyl cyanide, $CH_{2}=CHCH_{2}CN$, have been recorded for the gas, liquid and solid phases. Additionally, qualitative depolarization values were measured for the liquid phase. ... -
RAMAN AND INFRARED SPECTRA, CONFORMATIONAL STABILITY AND BARRIERS TO INTERNAL ROTATION OF 3–BROMO-2-METHYLPROPENE
Eltayeb, Saadia; Guirgis, G. A.; Durig, J. R. ( 1994 )The Raman (3200 to $20 cm^{-1})$ and infrared (3200 to $35 cm^{-1}$) spectra of 3-bromo-2-methylpropene, $H_{2}C=C(CH_{3}) CH_{2}Br$, have been recorded for the gas and solid. Additionally, the Raman spectrum of the liquid ... -
RAMAN AND INFRARED SPECTRA, CONFORMATIONAL STABILITY AND BARRIERS TO INTERNAL ROTATION OF TRIFLUOROACETYL ISOCYANATE
Krutules, K. A.; Guirgis, G. A.; Durig, J. R. ( 1994 )The Raman 3100 to $10 cm^{-1}$) and infrared (3100 to $30 cm^{-1}$) spectra of trifluoroacetyl isocyanate, $CF_{3}C(O)NCO$, have been recorded for the gas and solid. Additionally, the Raman spectrum of the liquid has been ... -
RAMAN AND INFRARED SPECTRA, CONFORMATIONAL STABILITY AND {AB INITIO} CALCULATIONS OF {TRANS}-1-FLUORO-2-BUTENE
Durig, D. T.; Zhen, Mengzhang; Durig, J. R. ( 1994 )The Raman (3200 to $10 cm^{-1}$) and infrared (3200to $20 cm^{-1}$) spectra of gaseous and solid {trans}-1-fluoro-2-butane, {trans}- $CH_{3}HC=CHCH_{2}F$, have been recorded. Additionally, the Raman spectrum of the liquid ... -
RAMAN AND INFRARED SPECTRA, CONFORMATIONAL STABILITY, AB INITIO CALCULATIONS AND VIBRATIONAL ASSIGNMENTS FOR CHLOROMETHYL METHYL SILANE
Nashed, Yasser E. ( 1998 )The infrared (3500 to $30 cm^{-1}$) spectra of gaseous and solid and the Raman (3500 to $10 cm^{-1}$) spectra of the liquid with quantitative depolarization ratios and solid chloromethyl methyl silane, $ClCH_{2}SiH_{2}CH_{3}$, ... -
RAMAN AND INFRARED SPECTRA, CONFORMATIONAL STABILITY, BARRIERS TO INTERNAL ROTATION, AND AB INITIO CALCULATIONS OF ACETYL ISOCYANATE
Krutules, K. A.; Durig, J. R.; Guirgis, G. A.; Sullivan, J. F. ( 1993 )The Raman (3100 to $10 cm^{-1}$) and infrared (3100 to $30 cm^{-1}$) spectra of acetyl isocyanate, $CH_{3}C(O)NCO$, and the $d_{3}$-isotopomer have been recorded for the gases and solids. Additionally, the Raman spectra ... -
RAMAN AND INFRARED SPECTRA, CONFORMATIONAL STABILITY, BARRIERS TO INTERNAL ROTATION, AND AB INITIO CALCULATIONS OF CROTYL CHLORIDE AND CROTYL BROMIDE
Durig, D. T.; Costner, T. G.; Goodson, H.; Frierson, G.; Durig, J. R. ( 1992 )The infrared (3200 to $40 cm^{-1}$) and Raman (3500 tp $10 cm^{-1}$) spectra have been recorded for the fluid and solid phases of crotyl chloride and crotyl bromide. These data have been interpreted on the basis that the ... -
RAMAN DIAGNOSTIC OF PHASE TRANSITIONS OF LIQUID CRYSTALS WITH DIFFERENT THERMAL PRE-HISTORY
Pogorelov, V. Ye.; Estrela-Llopis, I. B. ( 1995 )Structural peculiarities of liquid crystals (LC) depend essentially on the thermal pre-history of the sample. They specifically develop in the form and position of vibrational bands in Raman and IR absorption spectra. ... -
RAMAN FREQUENCIES OF THE TA PHONON MODE OF $NH_{4}Cl$ CLOSE TO PHASE TRANSITIONS
Yurtseven, H.; Sherman, W. F. ( 1992 )The Raman spectra of $TA_{M}$ ($93 cm^{-1}$) lattice mode of $NH_{4}Cl$ were obtained as functions of temperature in -
RAMAN FREQUENCY SHIFTS AND THE UODE GRONEISEN PARAMETER FOR THE TO MODE OF NH Cl NEAR PHASE TRANSITIONS
Yurtseven, H. ( 1993 )Raman frequency shifts for the $(144 cm^{-1})$ TO mode of $NH_{4}C1$ have been calculated at various temperatures for zero pressure near phase transitions $(P=O,T = 241.5 K)$ in this crystal system.By defining the mode ... -
RAMAN INVESTIGATION OF DYNAMICS OF POLYMORPHOUS TRANSFORMATIONS IN SUPERCOOLED LIQUID CRYSTALS
Pogorelov, V. Ye.; Estrela-Llopis, I. B.; Bulatov, V. P. ( 1995 )Phase transitions in liquid crystals (LC) influence on dinamic of intermolecular vibrations and it is manifested in changes of frequencies and shape of corresponding vibrational bands. Investigation results of temperature ... -
THE RAMAN SCATTERING INTENSITY PARAMETERS OF ACETYLENE
Gough, K. M.; Murphy, W. F. ( 1990 )The Raman trace scattering cross sections for CH strectching vibration may be described in terms of derivatives of the mean molecular polarizability with respect to the CH stretching internal coordinate. There is in general ... -
RAMAN SCATTERING STUDIES OF VIBRATIONAL ENERGY DISTRIBUTION IN LASER SUSTAINED PLASMAS
Lee, Wonchul; Adamovich, I.; Lempert, W. R. ( 1999 )It is well known that weakly ionized plasmas can be produced by CO laser irradiation of mixtures of CO in Argon. CO molecules in low vibrational levels directly absorb the CO laser radiation and undergo collisional up-pumping ... -
RAMAN SPECTRA AND CONFORMATIONAL STABILITY OF METHOXYDICHLOROPHOSPHINE.
Robb, J. B., II; Durig, J. R. ( 1994 )The Raman spectra (3500 to $30 cm^{-1}$) of gaseous and solid methoxydichlorophosphine, $CH_{3}OPCL_{2}$, have been recorded and only the {trans} conformer (methyl group {trans} to the phosphorus lone pair) is present in ...