Browsing Abstracts of OSU International Symposium on Molecular Spectroscopy 1990-1999 by Title
Now showing results 1404-1423 of 3912
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$I(^{2}P_{1/2})+I_{2}(X)$ ENERGY TRANSFER AND RE-ANALYSIS OF THE $I_{2}$ D-X SYSTEM.
Nowlin, M. L.; Heaven, M. C. ( 1993 )The electronic to vibrational energy transfer process $I(^{2}P_{1/2}) + I_{2}(X, \nu^{\prime \prime}=0) \rightarrow I(^{2}P_{3/2}) + I_{2}(X, 33<\nu^{\prime \prime}<44)$ is thought to play an important role in the chemical ... -
I-UNCOUPLING AND ROTATIONAL STRUCTURE IN VIBRATIONALLY AUTOIONIZING RYDBERG STATES OF HCO CONVERGING TO THE (010) LIMIT
Zuckerman, Eric J.; Hedderich, Hartmut G.; Grant, Edward R. ( 1999 )We have obtained $(1+1^{\prime})$ double resonance spectra autoionizing high Rydberg states of HCO. Scans originate from $3p\pi {^{2}}\Pi N=0-5$ intermediate states. These spectra cover Rydberg states of binding energies ... -
IDENTIFICATION AND ASSIGNMENTS OF LASER OPTOGALVANIC TRANSITIONS IN ATOMIC $ARGON^{a}$
Haridass, C.; Major, H. E.; She, Y.- B.; Misra, P. ( 1998 )The optogalvanic spectra of argon have been investigated in the ultraviolet region (290.88 - 320.75 nm) in an argon-containing commercial Laser Galvatron using a dye laser pumped by a Nd:YAG laser. Of the 102 optogalvanic ... -
IDENTIFICATION OF $^{17}O^{16}O^{16}O$ AND $^{16}O^{17}O^{16}O$ LINE IN INFRARED STRATOSPHERIC SOLAR ABSORPTION SPECTRA,
Rinsland, C. P.; Goldman, A.; Smith, M. A. H.; Perrin, A.; Heyard, M.; Flaud, J.- M.; Camy-Peyret, C.; Devi, V. Malathy; Murcray, F. J.; Murcray, D. G. ( 1992 )The 40\% enrichment in mid-stratospheric mass 50 ($^{16}O^{16}O^{18}O + ^{16}O^{18}O^{16}O$) heavy ozone measured in situ with a mass spectrometer by $Mauoresberger^{1}$ has motivated a large number of laboratory and ... -
IDENTIFICATION OF B AND C-TYPE CORIOLIS INTERACTIONS IN ${\tilde {A}^{1}A_{u}}$ ACETYLENE-$D_{2}$ USING DOUBLE RESONANCE SPECTROSCOPY
Lundberg, J. K.; Field, R. W. ( 1991 )The identification of B and C-type Coriolis interactions in the $\tilde{A} ^{1}{{A}_{u}}$ state is greatly facilitated by recording double resonance spectra to the vibrationless level of the previously assigned $\tilde {C} ... -
IDENTIFICATION OF THE $4P\sigma_{u} {^{1}\Pi_{u}}$ RYDBERG STATE OF $O_{2}$
England, J. P.; Lewis, B. R.; Ginter, M. L. ( 1995 )New high-resolution measurements of the $O_{2}$ photoabsorption cross section in the $1147 - 1155 {\AA}$ region are presented. The observation of three previously-unreported narrow lines in a band near $1148 {\AA}$ has ... -
IDENTIFICATION OF THE $^{3}\Sigma^{-}_{u}$ AND $^{3}\Pi_{u}$ RYDBERG STATES OF $O_{2}$ BY DETECTING $O(^{1}D)$
Nee, J. B.; Lee, P. C. ( 1997 )The excited states of $O_{2}$ in 100-135 nm region consists of many Rydberg states which are still not well understood. We have investigated the exited states of $O_{2}$ dissociated into $O(^{1}D)+O(^{3}P)$. The experiment ... -
IMAGING RAMAN SPECTROSCOPY AT HIGH RESOLUTION
Treado, Patrick J. ( 1998 )Raman spectroscopy has undergone a renaissance in the past several years due to key enabling technologies, including lasers, multichannel imaging detectors, and high performance Rayleigh scattering rejection filters. More ... -
IMPERFECT QUANTUM BIFURCATIONS
Kozin, I. N.; Zhilinskii, B.; Petrov, S. ( 1997 )Rotational multiplets of isolated vibrational molecular states can manifest qualitative modifications of their structure under the variation of some parameters. For instance, the quantum bifurcations have been found in the ... -
IMPLEMENTING A RIGOROUS WEIGHTING SCHEME FOR FITTING TO ROTATIONALLY RESOLVED SPECTRAL LINE POSITIONS
Keppler, Karen A.; Winnewisser, B. P.; Sarka, K. ( 1992 )Independent observations should be weighted according to the inverse of the squares of their uncertainties in any fitting procedure. For many types of spectroscopic experiments, uncertainties are not easy to determine. For ... -
THE IMPORTANCE OF NONADIABATIC EFFECTS IN CALCULATIONS AND ANALYSIS OF SPECTRA OF SMALL MOLECULES
Ogilvie, J. F. ( 1997 )We compare the results of calculations so called {ab initio} with pertinent experimental data, and demonstrate that nonadiabatic effects show comparable magnitudes to adiabatic effects in the spectral properties of small ... -
THE IMPORTANCE OF QUARTIC ANHARMONIC RESONANCES IN OVERTONE SPECTROSCOPY
Mills, Ian M. ( 1995 )Anharmonic resonances play a key role in our understanding of high overtone spectroscopy. The resonance polyads to which they give rise grow in dimension, and the magnitude of the coupling terms grow, as we ascend the ... -
IMPORTANCE OF SPECTROSCOPY FOR SPACE-BASED REMOTE SENSING
DeCola, Philip L. ( 1999 )Space-based remote sensing provides a powerful tool to study atmospheric trace constituent and aerosol distributions. A wide variety of spectroscopic techniques are used in these atmospheric composition measurements and ... -
AN IMPROVED DESIGN FOR A FOURIER TRANSFORM VIBRATIONAL CIRCULAR DICHROISM SPECTROMETER
Long, F.; Freedman, T. B.; Nafie, L. A. ( 1995 )A modified design for a Fourier Transform Vibrational Circular Dichroism (FTIR-VCD) $spectrometer^{1}$ based on a Nicolet Magna-IR 550 will be described. An external VCD bench incorporating lenses, polarizer, photoelastic ... -
IMPROVED DETERMINATION OF THE $Na-Ar X^{2}\Sigma$ INTERACTION POTENTIAL FROM LASERSPECTROSCOPY
Schwarzhans, D.; Zimmermann, D. ( 1998 )In a previous laserspectroscopic study of the $A^{2}\Pi \leftarrow X^{2}\Sigma$ transition of NaAr five vibrational levels $v = 0\ldots4$ of the $X^{2}\Sigma$ state have been $observed^{a}$. Recently, we have performed an ... -
AN IMPROVED FIT OF THE MICROWAVE SPECTRUM OF $SO_{2}-O_{2}$
Walker, A. R. Hight; Fraser, G. T.; Hougen, Jon T.; Suenram, R. D.; Fawzy, Wafaa M.; Novick, Stewart E. ( 1998 )The van der Waals complex, $SO_{2}-O_{2}$, has been studied by Fourier-transform microwave spectroscopy. Combination differences confirm the assignment of $74 a-$ and c-type transitions. The spectrum is complicated by a ... -
IMPROVED NONADIABATIC CALCULATION OF EXCITED SINGLET STATES OF THE HYDROGEN MOLECULE
Dressler, K.; Yu, Shiliang ( 1990 )Avoided crossings of the electronic energy curves of the $1\sigma_{u}{^{2}}$ state and of the Rydberg series $ns, nd\sigma (n-3,4\ldots)$ of hydrogen give rise to the double minima in the EF and $GK {^{1}}\Sigma_{g}^{+}$ ... -
IMPROVED OZONE LINE PARAMETERS FROM MICROWAVE TO MID-INFRARED
Flaud, J.- M.; Camy-Peyret, C.; Rinsland, C. P.; Smith, M. A. H.; Devi, V. Malathy ( 1990 )The ever increasing need for improvements in the accuracy of remote sensing measurements of ozone in the Earth's atmosphere has motivated the effort we began several years ago to undertake a comprehensive program to improve ... -
IMPROVED PARAMETERIZATION FOR DIATOMIC BORN-OPPENHEIMER BREAKDOWN EFFECTS, AND A NEW COMBINED-ISOTOPES ANALYSIS FOR HD AND DF
Le Roy, Robert J. ( 1997 )Although the Ross {et al.}$^{m}$-$Bunker^{n}$-$Watson^{o}$ expression for the vibration-rotation levels of isotopomers-$\alpha$ of diatomic molecule A-B, $E^{o}(\nu, J) =\sum_{l, m}\frac{V_{l,m}}{U_{a} ^{l,m1/2}}\left(1+ ... -
An improved potential energy surface for the interaction of $H_{2}$ with Ne
Crowell, Ken; Le Roy, Robert J.; McKellar, A. R. W. ( 1995 )For both the $H_{2}$ -Ne and $D_{2}$ -Ne Van der Waals bimers, new infrared spectra have been obtained in the region of the $H_{2} (or D_{2})$ monomer fundamental band region. We have used these new data in our least-squares ...