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dc.creatorHurley, Belinda L.
dc.creatorRalston, Kevin D.
dc.creatorBuchheit, Rudolph G.
dc.date.accessioned2014-08-15T16:18:23Z
dc.date.available2014-08-15T16:18:23Z
dc.date.issued2014-07-08
dc.identifier.citationHurley, Belinda L., Kevin D. Ralston, and Rudolph G. Buchheit, "Corrosion Inhibition of Zinc by Aqueous Vanadate Species," Journal of The Electrochemical Society 161, no. 10 (2014): C471-C475. DOI: 10.1149/2.0381410jesen_US
dc.identifier.issn1945-7111
dc.identifier.urihttp://hdl.handle.net/1811/61513
dc.description.abstractThis study presents a characterization of the degree and mechanism of corrosion inhibition of Zn by vanadate inhibitors. A combination of open circuit potential measurements, anodic and cathodic polarization, and Raman spectroscopy were used to compare corrosion inhibition of Zn exposed to or pre-treated with a dilute ∼pH 6.3 NaVO3+NaCl solution, which likely contained predominantly tetrahedrally coordinated vanadate species, relative to controls. The presence of vanadate caused a decrease in corrosion current density of up to two orders of magnitude due to overall mixed anodic and cathodic inhibition associated with the formation and/or stabilization of adherent surface films.en_US
dc.language.isoenen_US
dc.publisherElectrochemical Societyen_US
dc.rights© The Author(s) 2014. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution Non-Commercial No Derivatives 4.0 License (CC BY-NC-ND, http://creativecommons.org/licenses/by-nc-nd/4.0/), which permits non-commercial reuse, distribution, and reproduction in any medium, provided the original work is not changed in any way and is properly cited. For permission for commercial reuse, please email: oa@electrochem.org.en_US
dc.subjectvanadateen_US
dc.subjectcorrosionen_US
dc.subjectzincen_US
dc.subjectRamanen_US
dc.subjectpolarizationen_US
dc.titleCorrosion Inhibition of Zinc by Aqueous Vanadate Speciesen_US
dc.typeTexten_US
dc.description.embargoPublisher allows immediate open accessen_US
dc.identifier.doi10.1149/2.0381410jes
dc.type.genreArticleen_US


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