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dc.creatorAbbott, Heather L.en_US
dc.creatorBrathwaite, Antonio D.en_US
dc.creatorDuncan, Michael A.en_US
dc.date.accessioned2013-07-16T21:47:55Z
dc.date.available2013-07-16T21:47:55Z
dc.date.issued2013en_US
dc.identifier2013-MG-16en_US
dc.identifier.urihttp://hdl.handle.net/1811/55610
dc.descriptionAuthor Institution: Department of Chemistry and Biochemistry, Kennesaw State University, Kennesaw, GA 30144; Department of Chemistry, University of Georgia, Athens, GA 30602-2256en_US
dc.description.abstractRhodium carbonyl cations, Rh(CO)$_{n}^{+}$, and rhodium dinitrogen cations, Rh(N$_{2})_{n}^{+}$, are produced by laser vaporization in a pulsed-nozzle molecular beam source. Mass-selected infrared photodissociation spectroscopy of these ions and their argon tagged analogs are compared to density functional theory computations. Structures of the rhodium cations are determined based upon the number, frequency position and relative intensity of the infrared active bands between 2000 and 2400 cm$^{-1}$. Computed binding energies and fragmentation patterns suggest that four carbonyl ligands bind strongly to the central rhodium cation.en_US
dc.language.isoenen_US
dc.publisherOhio State Universityen_US
dc.titleINFRARED SPECTROSCOPY AND STRUCTURES OF MASS-SELECTED RHODIUM CARBONYL AND RHODIUM DINITROGEN CATIONSen_US
dc.typeArticleen_US
dc.typeImageen_US
dc.typePresentationen_US


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