Show simple item record

dc.creatorHodges, James N.en_US
dc.creatorPerry, Adam J.en_US
dc.creatorMcCall, Benjamin J.en_US
dc.date.accessioned2013-07-16T21:47:39Z
dc.date.available2013-07-16T21:47:39Z
dc.date.issued2013en_US
dc.identifier2013-MG-07en_US
dc.identifier.urihttp://hdl.handle.net/1811/55600
dc.descriptionAuthor Institution: Department of Chemistry, University of Illinois, Urbana, IL 61801; Departments of Chemistry, Astronomy, and Physics, University of Illinois, Urbana, IL 61801en_US
dc.description.abstractThe elusive methonium ion, CH$_5^+$, is of great interest due to its highly fluxional nature. The only published high-resolution infrared spectrum remains completely unassigned to this date. (1999) \textbf{284}, 135--137. } The primary challenge in understanding the CH$_5^+$ spectrum is that traditional spectroscopic approaches rely on a molecule having only small (or even large) amplitude motions about a well-defined reference geometry, and this is not the case with CH$_5^+$. \vspace{1em} We are in the process of re-scanning Oka's spectrum, in the original Black Widow discharge cell, using the new technique of Noise Immune Cavity Enhanced Optical Heterodyne Velocity Modulation Spectroscopy (NICE-OHVMS). \emph{Opt. Express} (2011), \textbf{19}, 24822--24827.} \emph{Chem. Phys. Lett.} (2012), \textbf{551}, 1--6.} The high precision afforded by optical saturation in conjunction with a frequency comb allows transition line centers to be determined with sub-MHz accuracy and precision -- a substantial improvement over the 90 MHz precision of Oka's work. \vspace{1em} With a high-precision linelist in hand, we plan to search for four line combination differences to directly determine the spacings between rotational energy levels. Such a search is currently infeasible due to the large number of false positives resulting from the relatively low precision and high spectral density of Oka's spectrum. The resulting combination differences, in conjunction with state-of-the-art theoretical calculations from Tucker Carrington,, (2008), \textbf{129}, 234102.} may provide the first insight into the rotational structure of this unique molecular system.en_US
dc.language.isoenen_US
dc.publisherOhio State Universityen_US
dc.titleHIGH PRECISION SPECTROSCOPY OF CH$_5^+$ USING NICE-OHVMSen_US
dc.typeArticleen_US
dc.typeImageen_US
dc.typePresentationen_US


Files in this item

Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail

Items in Knowledge Bank are protected by copyright, with all rights reserved, unless otherwise indicated.

This item appears in the following Collection(s)

Show simple item record