dc.creator Hodges, James N. en_US dc.creator Perry, Adam J. en_US dc.creator McCall, Benjamin J. en_US dc.date.accessioned 2013-07-16T21:47:39Z dc.date.available 2013-07-16T21:47:39Z dc.date.issued 2013 en_US dc.identifier 2013-MG-07 en_US dc.identifier.uri http://hdl.handle.net/1811/55600 dc.description Author Institution: Department of Chemistry, University of Illinois, Urbana, IL 61801; Departments of Chemistry, Astronomy, and Physics, University of Illinois, Urbana, IL 61801 en_US dc.description.abstract The elusive methonium ion, CH$_5^+$, is of great interest due to its highly fluxional nature. The only published high-resolution infrared spectrum remains completely unassigned to this date. (1999) \textbf{284}, 135--137. } The primary challenge in understanding the CH$_5^+$ spectrum is that traditional spectroscopic approaches rely on a molecule having only small (or even large) amplitude motions about a well-defined reference geometry, and this is not the case with CH$_5^+$. \vspace{1em} We are in the process of re-scanning Oka's spectrum, in the original Black Widow discharge cell, using the new technique of Noise Immune Cavity Enhanced Optical Heterodyne Velocity Modulation Spectroscopy (NICE-OHVMS). \emph{Opt. Express} (2011), \textbf{19}, 24822--24827.} \emph{Chem. Phys. Lett.} (2012), \textbf{551}, 1--6.} The high precision afforded by optical saturation in conjunction with a frequency comb allows transition line centers to be determined with sub-MHz accuracy and precision -- a substantial improvement over the 90 MHz precision of Oka's work. \vspace{1em} With a high-precision linelist in hand, we plan to search for four line combination differences to directly determine the spacings between rotational energy levels. Such a search is currently infeasible due to the large number of false positives resulting from the relatively low precision and high spectral density of Oka's spectrum. The resulting combination differences, in conjunction with state-of-the-art theoretical calculations from Tucker Carrington,, (2008), \textbf{129}, 234102.} may provide the first insight into the rotational structure of this unique molecular system. en_US dc.language.iso en en_US dc.publisher Ohio State University en_US dc.title HIGH PRECISION SPECTROSCOPY OF CH$_5^+$ USING NICE-OHVMS en_US dc.type Article en_US dc.type Image en_US dc.type Presentation en_US
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