NON-ADIABATIC ENERGIES OF THE HYDROGEN MOLECULE
Publisher:
Ohio State UniversityAbstract:
A novel perturbation theory has been developed to account for nonadiabatic effects in diatomic molecules, 164113 (2009)}. All molecular levels can be obtained simultanously from a single nuclear equation corrected for the presence of $(m/M)^2$ terms. Comparison with the direct nonadiabatic calculations for rotationless states of H$_2$ demonstrates an agreement at the level of $10^{-5}$ cm$^{-1}$ for the ground tone transition.
Description:
Author Institution: Faculty of Physics, University of Warsaw; Ho\.za 69, 00-681 Warsaw, Poland; Faculty of Chemistry, A. Mickiewicz University; Grunwaldzka 6, 60-780 Poznan, Poland
Type:
ArticleOther Identifiers:
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