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dc.creatorHatten, Courtney D.en_US
dc.creatorWarner, Brianen_US
dc.creatorWright, Emilyen_US
dc.creatorKaskey, Kevinen_US
dc.creatorKaskey, Kevinen_US
dc.creatorMcCunn, Laura R.en_US
dc.date.accessioned2013-07-16T21:39:26Z
dc.date.available2013-07-16T21:39:26Z
dc.date.issued2013en_US
dc.identifier2013-TE-11en_US
dc.identifier.urihttp://hdl.handle.net/1811/55358
dc.descriptionAuthor Institution: Department of Chemistry, Marshall University, Huntington, WV 25755en_US
dc.description.abstractThe thermal decomposition of butyraldehyde, CH$_3$CH$_2$CH$_2$C(O)H, has been studied in a resistively heated SiC tubular reactor. Products of pyrolysis were identified via matrix-isolation FTIR spectroscopy and photoionization mass spectrometry in separate experiments. Carbon monoxide, ethene, acetylene, water and ethylketene were among the products detected. To unravel the mechanism of decomposition, pyrolysis of a partially deuterated sample of butyraldehyde was studied. Also, the concentration of butyraldehyde in the carrier gas was varied in experiments to determine the presence of bimolecular reactions. The results of these experiments can be compared to the dissociation pathways observed in similar aldehydes and are relevant to the processing of biomass, foods, and tobacco.en_US
dc.language.isoenen_US
dc.publisherOhio State Universityen_US
dc.titleTHERMAL DECOMPOSITION MECHANISM OF BUTYRALDEHYDEen_US
dc.typeArticleen_US
dc.typeImageen_US
dc.typePresentationen_US


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