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dc.creatorMessinger, Joseph P.en_US
dc.creatorKnowlton, Gregory S.en_US
dc.creatorSundheim, Kathryn M.en_US
dc.creatorLeung, Helen O.en_US
dc.creatorMarshall, Mark D.en_US
dc.date.accessioned2013-07-16T21:38:14Z
dc.date.available2013-07-16T21:38:14Z
dc.date.issued2013en_US
dc.identifier2013-TC-03en_US
dc.identifier.urihttp://hdl.handle.net/1811/55323
dc.descriptionAuthor Institution: Department of Chemistry, Amherst College, P.O. Box 5000, Amherst, MA 01002-5000en_US
dc.description.abstractChirped-pulse and Balle-Flygare spectrometers are used to obtain Fourier transform microwave spectra of 2-chloro-1,1-difluoroethylene and its complex with argon from 5.5 to 21.0 GHz, allowing for the geometries of both species to be determined. A total of six isotopologues are observed each for the monomer and dimer, including the most abundant species, the singly-substituted $^{37}$Cl and two singly-substituted $^{13}$C isotopologues in natural abundance, and deuterated versions of both the $^{35}$Cl and $^{37}$Cl species using an isotopically enriched sample. Similar to the previously studied argon-haloethylene complexes, the argon shows a preference for close contact with heavier atoms. Tunneling of the argon between two equivalent non-planar structures, similar to that in argon-{\it cis}-1,2-difluoroethylene, is not observed in this complex.en_US
dc.language.isoenen_US
dc.publisherOhio State Universityen_US
dc.titleMICROWAVE SPECTRA AND MOLECULAR STRUCTURES OF 2-CHLORO-1,1-DIFLUOROETHYLENE AND ITS COMPLEX WITH ARGONen_US
dc.typeArticleen_US


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