MICROWAVE SPECTRA OF FLUORINATED PROPIONIC ACIDS AND THEIR HYDRATES
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Creators:
Obenchain, Daniel A.Grubbs, G. S., II
Novick, Stewart E.
Cooke, Stephen A.
Serrato, Agapito III
Lin, Wei
Issue Date:
2013Metadata
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Ohio State UniversityAbstract:
The microwave spectra of three fluorinated propionic acids, namely pentafluoropropionic acid, 2,2,3,3-tetrafluoropropionic acid, and 2,3,3,3-tetrafluoropropionic acid have been observed and assigned. The spectra of pentafluoropropionic acid and its monohydrate were reported in this meeting last year. The conformational analysis of 2,2,3,3-tetrafluoropropionic acid and 2,3,3,3-tetrafluoropropionic acid will be compared to that of pentafluoropropionic acid. The structures of the three monohydrates will be discussed in terms of hydrogen bonding.
Description:
Author Institution: Department of Chemistry, Wesleyan University, Middletown, CT 06459; School of Natural and Social Sciences, Purchase College, SUNY, 735 Anderson Hill Road, Purchase, NY 10577; Department of Chemistry and Environmental Science, University of Texas at Brownsville, Brownsville, TX 78520
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