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dc.creatorAdande, Gillesen_US
dc.creatorZiurys, L. M.en_US
dc.date.accessioned2013-07-16T21:32:11Z
dc.date.available2013-07-16T21:32:11Z
dc.date.issued2013en_US
dc.identifier2013-RC-07en_US
dc.identifier.urihttp://hdl.handle.net/1811/55165
dc.descriptionAuthor Institution: Department of Chemistry, Steward Observatory University of Arizona, Tucson, 85721en_US
dc.description.abstractThe pure rotational spectrum of VS (X$^{4}\Sigma^{-} $) has been measured with Fourier transform microwave (FTMW) and millimeter-wave direct absorption methods in the frequency range of 5-40 GHz and 210-315 GHz. Discharge assisted laser ablation (DALAS) of a vanadium rod in presence of H$_{2}$S gas was used to synthesize the radical in the microwave region. In the millimeter-wave range, the species was produced from the mixture of CS$_{2}$ and VCl$_{4}$ vapor in a DC discharge. The hyperfine structure was resolved and accurate fine and hyperfine parameters were obtained. Insights into the bonding character can be gleamed from the hyperfine constants, and an estimate of the position of two low-lying interacting electronic states can be obtain from the fine structure parameters. Details of these results will be discussed.en_US
dc.language.isoenen_US
dc.publisherOhio State Universityen_US
dc.titleTHE MILLIMETER DIRECT ABSORPTION AND FOURIER TRANSFORM MICROWAVE SPECTRUM OF VANADIUM SULFIDE (X$^{4}\Sigma^{-}$)en_US
dc.typeArticleen_US


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