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dc.creatorObi, Emmanuel I.en_US
dc.creatorDouberly, Gary E.en_US
dc.date.accessioned2013-07-16T21:31:51Z
dc.date.available2013-07-16T21:31:51Z
dc.date.issued2013en_US
dc.identifier2013-RB-08en_US
dc.identifier.urihttp://hdl.handle.net/1811/55153
dc.descriptionAuthor Institution: Department of Chemistry, University of Georgia, Athens, Georgia 30602, USAen_US
dc.description.abstractThe weakly bound complexes X-O$_{3}$ (X=OH, C$_{2}$H$_{4}$) have been isolated in helium nanodroplets and probed with infrared laser spectroscopy. Measurements are carried out in the high frequency OH/CH stretch region (2900-3600 cm$^{-1}$) and in the OOO symmetric and antisymmetric stretch region near 1050 cm$^{-1}$. Many of the observed bands exhibit rotational fine structure, allowing for structural assignments via Stark spectroscopy. Rotationally resolved vibrational bands of the OH-O$_{3}$ complex indicate a rather weak interaction, as the orbital angular momentum of the unpaired electron is unquenched and remains strongly coupled to the OH bond axis.en_US
dc.language.isoenen_US
dc.publisherOhio State Universityen_US
dc.titleROVIBRATIONAL SPECTROSCOPY OF THE OH-O$_{3}$ AND C$_{2}$H$_{4}$-O$_{3}$ COMPLEXES IN $^{4}$He NANODROPLETSen_US
dc.typeArticleen_US


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