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dc.creatorShishido, Ryunosukeen_US
dc.creatorFujii, Asukaen_US
dc.creatorKuo, Jer-Laien_US
dc.date.accessioned2013-07-16T21:30:50Z
dc.date.available2013-07-16T21:30:50Z
dc.date.issued2013en_US
dc.identifier2013-MK-02en_US
dc.identifier.urihttp://hdl.handle.net/1811/55119
dc.descriptionAuthor Institution: Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan; Institute of Atomic and Molecular Science, Academia Sinica, Taipei 10617, Taiwanen_US
dc.description.abstractThe magic number behavior of ((CH${_3}$)${_3}$N)${_n}$-H$^{+}$-H${_2}$O clusters at n = 3 is investigated by applying infrared spectroscopy to the clusters of n = 1-3. nderline{\textbf{116}}, 6740, 2012.} Structures of these clusters are determined in conjunction with density functional theory calculations. Dissociation channels upon infrared excitation are also measured, and their correlation with the cluster structures is examined. It is demonstrated that the magic number cluster has a closed-shell structure, in which the water moiety is surrounded by three (CH${_3}$)${_3}$N molecules. Large rearrangement of the cluster structures of n = 2 and 3 before dissociation, which has been suggested in the mass spectrometric study, nderline{\textbf{113}}, 1960, 1991.} is confirmed on the basis of the structure determination by infrared spectroscopy.en_US
dc.language.isoenen_US
dc.publisherOhio State Universityen_US
dc.titleINFRARED SPECTROSCOPY OF ((CH${_3}$)${_3}$N)${_n}$-H$^{+}$-H${_2}$O (n=1-3): STRUCTURES AND DISSOCIATION CHANNELS OF PROTONATED MIXED CLUSTERS AROUND A MAGIC NUMBERen_US
dc.typeArticleen_US
dc.typeImageen_US
dc.typePresentationen_US


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