dc.creator Shishido, Ryunosuke en_US dc.creator Fujii, Asuka en_US dc.creator Kuo, Jer-Lai en_US dc.date.accessioned 2013-07-16T21:30:50Z dc.date.available 2013-07-16T21:30:50Z dc.date.issued 2013 en_US dc.identifier 2013-MK-02 en_US dc.identifier.uri http://hdl.handle.net/1811/55119 dc.description Author Institution: Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan; Institute of Atomic and Molecular Science, Academia Sinica, Taipei 10617, Taiwan en_US dc.description.abstract The magic number behavior of ((CH${_3}$)${_3}$N)${_n}$-H$^{+}$-H${_2}$O clusters at n = 3 is investigated by applying infrared spectroscopy to the clusters of n = 1-3. nderline{\textbf{116}}, 6740, 2012.} Structures of these clusters are determined in conjunction with density functional theory calculations. Dissociation channels upon infrared excitation are also measured, and their correlation with the cluster structures is examined. It is demonstrated that the magic number cluster has a closed-shell structure, in which the water moiety is surrounded by three (CH${_3}$)${_3}$N molecules. Large rearrangement of the cluster structures of n = 2 and 3 before dissociation, which has been suggested in the mass spectrometric study, nderline{\textbf{113}}, 1960, 1991.} is confirmed on the basis of the structure determination by infrared spectroscopy. en_US dc.language.iso en en_US dc.publisher Ohio State University en_US dc.title INFRARED SPECTROSCOPY OF ((CH${_3}$)${_3}$N)${_n}$-H$^{+}$-H${_2}$O (n=1-3): STRUCTURES AND DISSOCIATION CHANNELS OF PROTONATED MIXED CLUSTERS AROUND A MAGIC NUMBER en_US dc.type Article en_US dc.type Image en_US dc.type Presentation en_US
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