PHOTODISSOCIATION DYNAMICS OF 2-BROMOETHYLNITRITE AT 351 NM AND C-C BOND FISSION IN THE $\beta $-BROMOETHOXY RADICAL PRODUCT
dc.creator | Wang, Lei | en_US |
dc.creator | Chhantyal-Pun, Rabi | en_US |
dc.creator | Brynteson, Matt D. | en_US |
dc.creator | Miller, Terry A. | en_US |
dc.creator | Butler, Laurie J. | en_US |
dc.date.accessioned | 2013-07-16T21:30:40Z | |
dc.date.available | 2013-07-16T21:30:40Z | |
dc.date.issued | 2013 | en_US |
dc.identifier | 2013-MJ-15 | en_US |
dc.identifier.uri | http://hdl.handle.net/1811/55116 | |
dc.description | Author Institution: Department of Chemistry, The University of Chicago, Chicago, IL 60637; Department of Chemistry, The Ohio State University, Columbus, OH 43210; Department of Chemistry, The University of Chicago, Chicago, IL 60637; Department of Chemistry, The Ohio State University, Columbus, OH 43210; Department of Chemistry, The University of Chicago, Chicago, IL 60637 | en_US |
dc.description.abstract | We used a crossed laser-molecular beam scattering experiment to investigate the primary photodissociation channels of bromoethylnitrite at 351 nm. Only the O-NO bond fission channel forming the $\beta $-bromoethoxy radical and NO, no HBr photoelimination, was detected upon 351 nm photoexcitation,. The subsequent decomposition of the highly vibrational excited $\beta $-bromoethoxy radical to formaldehyde + CH${_2}$Br was also investigated. | en_US |
dc.language.iso | en | en_US |
dc.publisher | Ohio State University | en_US |
dc.title | PHOTODISSOCIATION DYNAMICS OF 2-BROMOETHYLNITRITE AT 351 NM AND C-C BOND FISSION IN THE $\beta $-BROMOETHOXY RADICAL PRODUCT | en_US |
dc.type | Article | en_US |
dc.type | Image | en_US |
dc.type | Presentation | en_US |
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