Show simple item record

dc.creatorKumari, Sudeshen_US
dc.creatorSohnlein, Braden_US
dc.creatorYang, Dong-Shengen_US
dc.date.accessioned2012-07-09T19:41:48Z
dc.date.available2012-07-09T19:41:48Z
dc.date.issued2012en_US
dc.identifier2012-WJ-04en_US
dc.identifier.urihttp://hdl.handle.net/1811/52543
dc.descriptionAuthor Institution: Department of Chemistry, University of Kentucky, Lexington, KY 40506-0055en_US
dc.description.abstractGroup III metal-aniline complexes, M-aniline (M = Sc, Y, and La), were produced by interactions between laser-vaporized metal atoms and aniline vapor in a pulsed molecular beam source, identified by photoionization time-of-flight mass spectrometry, and studied by pulsed-field ionization zero electron kinetic energy (ZEKE) spectroscopy and density functional theory calculations. Adiabatic ionization energies and several vibrational intervals were measured from the ZEKE spectra. Metal binding sites and electronic states were determined by combining the ZEKE measurements and theoretical calculations. Although aniline has various possible sites for metal coordination, the preferred site was determined to be phenyl ring. The metal binding with the phenyl ring yields \emph{syn} and \emph{anti} conformers. In these conformers, the neutral complexes are in doublet ground states and the corresponding singly charged cations in singlet states.en_US
dc.language.isoenen_US
dc.publisherOhio State Universityen_US
dc.titlePREFERRED METAL BINDING SITE OF ANILINEen_US
dc.typeArticleen_US
dc.typeImageen_US
dc.typePresentationen_US


Files in this item

Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail

Items in Knowledge Bank are protected by copyright, with all rights reserved, unless otherwise indicated.

This item appears in the following Collection(s)

Show simple item record