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dc.creatorShishido, Ryunosukeen_US
dc.creatorFujii, Asukaen_US
dc.creatorJer-Lai, Kuoen_US
dc.date.accessioned2012-07-09T19:25:38Z
dc.date.available2012-07-09T19:25:38Z
dc.date.issued2012en_US
dc.identifier2012-TE-06en_US
dc.identifier.urihttp://hdl.handle.net/1811/52392
dc.descriptionAuthor Institution: Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan; Institute of Atomic and Molecular Sciences Academia Sinica, Taipei, Taiwanen_US
dc.description.abstractThe magic number behavior of H$^+$(H$_2$O)$_{21}$ has been well known. Futhermore, this magic number is observed even in the mixed clusters H$^+$(H$_2$O)$_m$(NH$_3$)$_n$ and H$^+$(H$_2$O)$_m$(MeOH)$_n$ (m $+$ n $=$ 21). This means that NH$_3$ or MeOH molecules are compatible with water molecules in the hydrogen bond network of the magic number cluster.\ In the present study, infrared spectroscopy is applied to (CH$_3$)$_3$N-H$^+$-(H$_2$O)$_n$ (n $=$ 1-22), and structures of these clusters are determined with help of density functional theory calculations. As a result, it is demonstrated that no magic number is seen in the case of (CH$_3$)$_3$N-H$^+$-(H$_2$O)$_n$. (CH$_3$)$_3$N is not a spectator to the hydrogen bond network of protonated water clusters, and it is largely changes the network structure.en_US
dc.language.isoenen_US
dc.publisherOhio State Universityen_US
dc.titleINFRARED SPECTROSCOPY OF (CH$_3$)$_3$N-H$^+$-(H$_2$O)$_n$ (n $=$ 1-22)en_US
dc.typeArticleen_US
dc.typeImageen_US
dc.typePresentationen_US


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