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dc.creatorBrown-Xu, Samantha E.en_US
dc.creatorDurr, Christopher B.en_US
dc.date.accessioned2012-07-09T19:19:15Z
dc.date.available2012-07-09T19:19:15Z
dc.date.issued2012en_US
dc.identifier2012-FB-11en_US
dc.identifier.urihttp://hdl.handle.net/1811/52325
dc.descriptionAuthor Institution: The Ohio State University, Department of Chemistry and Biochemistry, Columbus, Ohio 43210en_US
dc.description.abstractCompounds of the form M_{2}$L_{2}$L'_{2}$, where M_{2}$ is a quadruply bonded metal center (M = Mo or W) and L and L' are conjugated organic ligands, are known to show interesting photophysical properties and exhibit intense metal-to-ligand charge transfer (MLCT) transitions throughout the visible spectrum. Recently, we have modified one of the ligands to incorporate a transition metal carbonyl complex bound to an organic moiety. Following excitation into the MLCT band, the vibrational modes of the organometallic ligand can be observed by fs time-resolved infrared (TRIR) spectroscopy. This allows for a visualization of where the electron density resides in the excited states, which provides useful information for designing new materials that could later be incorporated into solar devices.en_US
dc.language.isoenen_US
dc.publisherOhio State Universityen_US
dc.titleFEMTOSECOND TIME-RESOLVED INFRARED SPECTRA OF ORGANOMETALLIC COMPLEXES BOUND TO A DINUCLEAR METAL CENTERen_US
dc.typeArticleen_US
dc.typeImageen_US
dc.typePresentationen_US


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