APPLICATION OF EQUATION-OF-MOTION COUPLED-CLUSTER THEORY TO PHOTODETACHMENT CROSS SECTION CALCULATIONS
Publisher:
Ohio State UniversityAbstract:
Photodetachment cross sections of atomic anions have been calculated with equation-of-motion coupled-cluster (EOM-CC) theory. Two techniques have been examined. One of them treats the photodetached electron as a plane wave, and the transition moment integral is evaluated with the Dyson orbital obtained from EOMIP-CC calculations. In the other technique, the EOM-EE method is utilized to calculate the oscillator strengths for photodetachment processes within the framework of moment theory. The results of these calculations are compared with experimental results, and the pros and cons of the two techniques are discussed.
Description:
Author Institution: Department of Chemistry and Biochemistry, The University of Texas at Austin, Austin, TX 78712
Type:
ArticleImage
Presentation
Other Identifiers:
2012-MI-11Items in Knowledge Bank are protected by copyright, with all rights reserved, unless otherwise indicated.