dc.creator Kisiel, Zbigniew en_US dc.creator Kraśnicki, Adam en_US dc.date.accessioned 2011-07-12T17:39:45Z dc.date.available 2011-07-12T17:39:45Z dc.date.issued 2011 en_US dc.identifier 2011-MH-06 en_US dc.identifier.uri http://hdl.handle.net/1811/49681 dc.description Author Institution: Institute of Physics, Polish Academy of Sciences, Al. Lotnikow; 32/46, 02-668 Warszawa, Poland en_US dc.description.abstract Previous determinations of the electric dipole moment of acrylonitrile, while in agreement on the total dipole moment, showed an appreciable difference in the value of the smaller $\mu_b$ component., {\bf 22}, 516 (1954)}$^,$, {\bf 40a}, 998 (1985)} The value of this component is important for intensity considerations in the THz spectrum of this molecule, which is dominated by $b$-type transitions. {\bf 258}, 26 (2009).} \vspace{0.2cm} We decided to update the dipole moment determination of acrylonitrile, and also of propionitrile (ethyl cyanide) by making Stark measurements in supersonic expansion. We used the Stark electrode arrangement developed in our laboratory and the program QSTARK for fitting Stark measurements on resolved nuclear quadrupole hyperfine structure. {\bf 325}, 523 (2000).} The results for acrylonitrile show a further, significant difference in the value of $\mu_b$, while those for propionitrile, while more precise, are essentially consistent with previous values., {\bf 29a}, 1345 (1974)} The evidence from $ab~initio$ calculations and from relative intensity measurements supporting the current dipole moment determinations is presented. en_US dc.language.iso en en_US dc.publisher Ohio State University en_US dc.title IMPROVED DIPOLE MOMENTS FOR ACRYLONITRILE AND PROPIONITRILE en_US dc.type Article en_US dc.type Image en_US dc.type Presentation en_US
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