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dc.creatorLawson, Michael A.en_US
dc.creatorHoffman, Kristian J.en_US
dc.creatorDavies, Paul B.en_US
dc.date.accessioned2011-07-12T17:38:14Z
dc.date.available2011-07-12T17:38:14Z
dc.date.issued2011en_US
dc.identifier2011-WJ-03en_US
dc.identifier.urihttp://hdl.handle.net/1811/49619
dc.descriptionAuthor Institution: Department of Chemistry, University of Cambridge, Lensfield Road; Cambridge, CB2 1EW, U.K.en_US
dc.description.abstractThe infrared absorption spectrum associated with the asymmetric stretching fundamental of PO$_2$ ($v_3$) has been measured using high resolution tunable diode laser spectroscopy. The free radical was formed in large concentrations in a fast-flow system by reacting white phosphorus vapour with atomic oxygen. More than 700 new lines have been assigned between 1290 and 1350 cm$^{-1}$. Data was combined with infrared and LMR lines, obtained from previous studies and simultaneously fitted using the CALPGM suite. The precise constants derived definitively exclude a series of unassigned transitions from belonging to the $v_3$ fundamental band and potential assignments for that series are discussed.en_US
dc.language.isoenen_US
dc.publisherOhio State Universityen_US
dc.titleHIGH RESOLUTION INFRARED SPECTROSCOPY OF THE PO$_2$ RADICALen_US
dc.typeArticleen_US
dc.typeImageen_US
dc.typePresentationen_US


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