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dc.creatorYoung, Justin W.en_US
dc.creatorPratt, David W.en_US
dc.date.accessioned2011-07-12T17:32:51Z
dc.date.available2011-07-12T17:32:51Z
dc.date.issued2011en_US
dc.identifier2011-TG-09en_US
dc.identifier.urihttp://hdl.handle.net/1811/49496
dc.descriptionWork supported by NSF(CHE-0911117).en_US
dc.descriptionAuthor Institution: Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15260en_US
dc.description.abstract7-azaindole readily forms water clusters when seeded into a molecular beam. Interestingly, the addition of water considerably perturbs the excited state of 7-azaindole: the electronic origin of 7-azaindole(H$_2$O) is shifted drastically to lower energy, ~1290 \wn, relative to the origin of the bare molecule; furthermore, recent evidence indicates that 7-azaindole(H$_2$O) is of \textit{L$_a$} character, contrary to the bare molecule. \textbf{128}, 214311 (2008).} In this work, high resolution electronic spectra of 7-azaindole(H$_2$O) were measured in the presence of an external electric field , as a means to study water induced changes in the electronic distribution of 7-azaindole. Furthermore, the \textit{L$_a$/L$_b$} character of the excited state of 7-azaindole(H$_2$O) was examined by recording similar spectra of isotopically labeled species.en_US
dc.language.isoenen_US
dc.publisherOhio State Universityen_US
dc.titleEXCITED STATE PERTURBATIONS OF 7-AZAINDOLE MEDIATED THROUGH MICRO-SOLVATION.en_US
dc.typeArticleen_US
dc.typeImageen_US
dc.typePresentationen_US


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