Show simple item record

dc.creatorTokaryk, D. W.en_US
dc.creatorCulligan, S. D.en_US
dc.creatorBillinghurst, B. E.en_US
dc.creatorWijngaarden, J. A. Vanen_US
dc.date.accessioned2011-07-12T17:28:33Z
dc.date.available2011-07-12T17:28:33Z
dc.date.issued2011en_US
dc.identifier2011-RG-14en_US
dc.identifier.urihttp://hdl.handle.net/1811/49357
dc.descriptionAuthor Institution: Department of Physics and Centre for Laser, Atomic and Molecular Sciences, University of New Brunswick, Fredericton, NB, Canada E3B 5A3; Canadian Light Source, Inc., 101 Perimeter Road, University of Saskatchewan, Saskatoon, SK, Canada S7N 0X4; Department of Chemistry, University of Manitoba, Winnipeg, MB, Canada R3T 2N2en_US
dc.description.abstractThe $\nu_{14}$ vibrational level of furan lies 603 cm$^{-1}$ above the ground vibrational state. It is the lowest lying vibrational level for which a transition from the ground state is allowed. Other groups have conducted rotational analyses on fundamental bands of furan at 745 cm$^{-1}$ ($\nu_{13}$) \textbf{48} (1993) 1193--1202.}, 995 cm$^{-1}$ ($\nu_{7}$) \textbf{198} (1999) 348--357.} and at 1067 cm$^{-1}$ ($\nu_{6}$) \textbf{209} (2001) 136--138.}. We have taken the rotationally resolved spectrum of the \textit{c}-type $\nu_{14}$ band at the Canadian Light Source synchrotron with a Bruker IFS125HR Fourier transform spectrometer operating at 0.00096 cm$^{-1}$ resolution, and have found it to be perturbed by the $\nu_{11}$ band at 600 cm$^{-1}$, for which transitions from the ground vibrational state are forbidden. By taking the spectra of the \textit{b}-type $\nu_{18}$ fundamental band and of the very weak \textit{c}-type $\nu_{18}$- $\nu_{11}$ band we have been able to analyze the $\nu_{14}$- $\nu_{11}$ perturbation. We have also analyzed the spectrum of the \textit{b}-type $\nu_{19}$ fundamental band.en_US
dc.language.isoenen_US
dc.publisherOhio State Universityen_US
dc.titleFAR-INFRARED SYNCHROTRON-BASED SPECTROSCOPY OF FURAN: ANALYSIS OF THE $\nu_{14}-\nu_{11}$ PERTURBATION AND THE $\nu_{18}$ AND $\nu_{19}$ LEVELSen_US
dc.typeArticleen_US
dc.typeImageen_US
dc.typePresentationen_US


Files in this item

Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail

Items in Knowledge Bank are protected by copyright, with all rights reserved, unless otherwise indicated.

This item appears in the following Collection(s)

Show simple item record