TORSIONAL EXCITATION IN O-H STRETCH OVERTONE SPECTRA OF ETHYL HYDROPEROXIDE CONFORMERS
MetadataShow full item record
Publisher:Ohio State University
Photoacoustic spectra at 3-6 quanta of O-H stretch show features attributed to torsion about the O-O bond and to distinct contributions from two conformers. Laser-induced fluorescence detection of OH radicals demonstrates unimolecular dissociation from some vibrationally and torsionally excited states.
Author Institution: Chemistry Department, Smith College, Northampton, MA 01063
Items in Knowledge Bank are protected by copyright, with all rights reserved, unless otherwise indicated.