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dc.creatorKumar, Girdhari
dc.creatorBuchheit, Rudolph G
dc.date.accessioned2011-07-08T13:48:12Z
dc.date.available2011-07-08T13:48:12Z
dc.date.issued2005-10
dc.identifier.citationGirdhari Kumar and Rudolph G Buchheit, "Development and Characterization of Corrosion Resistant Coatings Using the Natural Biopolymer Chitosan," ECS Transactions 1, no. 9 (2005), doi:10.1149/1.2215582en_US
dc.identifier.issn1938-6737
dc.identifier.urihttp://hdl.handle.net/1811/49187
dc.description.abstractIn the present study, chitosan was used as the basis for corrosion resistant coating. Chitosan suffers from two inherent weaknesses as a coating material namely high hydrophilicity and poor adhesive strength with Al 2024 T3 alloy. In the present study, chitosan structure was modified using epoxy functional silane and vanadate. Performance of coatings was tested using EIS, adhesion testing and salt spray testing. The best salt spray performance was observed in case of chitosan-(3-Glycidoxypropyl)-trimethoxysilane-vanadate coatings, which lasted 450 hours in salt spray chamber. UV/Visible measurements showed release of vanadate by chitosan increases with increasing solution pH. This property of chitosan provides self-healing characteristics to these coatings. When the solution pH is readjusted to a lower value, chitosan can re-adsorb released vanadate. FTIR spectra of chitosan gel showed adsorption of vanadate at protonated amine sites. Chitosan showed a maximum in the vanadate adsorption capacity in the pH 3 to 5 range.en_US
dc.language.isoen_USen_US
dc.publisherThe Electrochemical Societyen_US
dc.rights© The Electrochemical Society, Inc. 2006. All rights reserved. Except as provided under U.S. copyright law, this work may not be reproduced, resold, distributed, or modified without the express permission of The Electrochemical Society (ECS). The archival version of this work was published in ECS Transactions, 1 (9) 101-117.en_US
dc.titleDevelopment and Characterization of Corrosion Resistant Coatings Using the Natural Biopolymer Chitosanen_US
dc.typeArticleen_US
dc.identifier.doi10.1149/1.2215582
dc.identifier.osuauthorbuchheit.8


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