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dc.creatorRoudjane, Mouraden_US
dc.creatorKumari, Sudeshen_US
dc.creatorYang, Dong-Shengen_US
dc.date.accessioned2010-07-12T14:31:27Z
dc.date.available2010-07-12T14:31:27Z
dc.date.issued2010en_US
dc.identifier2010-MH-10en_US
dc.identifier.urihttp://hdl.handle.net/1811/46422
dc.descriptionAuthor Institution: Department of chemistry, University of Kentucky, Lexington, KY 40506-0055en_US
dc.description.abstractOver the last 25 years, organometallic chemistry of $f$ elements has attracted considerable attentions of both experimentalists and theoreticians. We have recently succeeded in producing Ln-benzene (Ln $=$ Lu, Gd) complexes in laser-vaporization supersonic molecular beams and in measuring their vibronic spectra using single-photon pulsed field ionization-zero electron kinetic energy (PFI-ZEKE) spectroscopy. We obtained for the first time the adiabatic ionization energy (AIE) and metal-benzene vibrational frequencies. The AIE of the Lu-benzene complex is 44461 (5) cm$^{-1}$, and the Lu-benzene stretching frequencies are 204 and 270 cm$^{-1}$ in the neutral and ion, respectively. For the Gd-benzene complex, its AIE is 40830 (5) cm$^{-1}$, and the metal-ligand stretching frequencies of the neutral and ionic species are 256 and 298 cm$^{-1}$. We will discuss the electronic transitions involved in the PFI-ZEKE spectra of the two complexes by combining the experimental measurements with quantum chemical calculations and spectral simulations.en_US
dc.language.isoenen_US
dc.publisherOhio State Universityen_US
dc.titlePULSED-FIELD IONOZATION ELECTRON SPECTROSCOPY OF LANTHANIDE (Lu, Gd) BENZENE COMPLEXESen_US
dc.typeArticleen_US
dc.typeImageen_US
dc.typePresentationen_US


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