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dc.creatorShirar, Amanda J.en_US
dc.creatorHotopp, Kelly M.en_US
dc.creatorWilcox, David S.en_US
dc.creatorDian, Brian C.en_US
dc.date.accessioned2010-07-12T14:27:10Z
dc.date.available2010-07-12T14:27:10Z
dc.date.issued2010en_US
dc.identifier2010-TC-08en_US
dc.identifier.urihttp://hdl.handle.net/1811/46383
dc.descriptionAuthor Institution: Department of Chemistry, Purdue University, West Lafayette, IN, 47907en_US
dc.description.abstractThere is a gap in the electromagnetic spectrum where the microwave region is located when considering broadband two-dimensional spectroscopy. We introduce two-dimensional chirped-pulse Fourier transform microwave (CP-FTMW) spectroscopy as a way to directly identify coherences between coupled rotational levels. The theory and application of these experiments is a direct extension of traditional two-dimensional NMR techniques. Several different pulse sequences will be presented that allow for selective (narrowband) and non-selective (broadband) excitation. Data acquisition with broadband (10 GHz) detection enables several coupled transitions to be monitored simultaneously. Due to the extremely large amount of data acquired in each experiment, a new way of processing data is explained that allows a more straightforward analysis of the spectra. An autocorrelation study of 1-chloro-1-fluoroethylene is presented as a simple example of this application in the microwave region of the spectrum.en_US
dc.language.isoenen_US
dc.publisherOhio State Universityen_US
dc.titleTWO-DIMENSIONAL CHIRPED-PULSE FOURIER TRANSFORM MICROWAVE SPECTROSCOPY: INTRODUCTION TO TWO-DIMENSIONAL BROADBAND TECHNIQUESen_US
dc.typeArticleen_US
dc.typeImageen_US
dc.typePresentationen_US


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