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dc.creatorWilcox, David S.en_US
dc.creatorHotopp, Kelly M.en_US
dc.creatorShirar, Amanda J.en_US
dc.creatorDian, Brian C.en_US
dc.date.accessioned2010-07-12T14:24:05Z
dc.date.available2010-07-12T14:24:05Z
dc.date.issued2010en_US
dc.identifier2010-TC-09en_US
dc.identifier.urihttp://hdl.handle.net/1811/46356
dc.descriptionAuthor Institution: Department of Chemistry, Purdue University, West Lafayette, IN, 47907en_US
dc.description.abstractTwo-dimensional broadband techniques have been introduced into the microwave regime using chirped-pulse Fourier transform spectroscopy. Theoretical considerations of expanding the prototypical three-level model to an N-level system are presented. Representative Hamiltonian and density matrices were used to solve the Liouville-von Neumann equations of motion in order to describe the evolution of coherently prepared states. Several selective excitation pulse sequences were performed on 1-chloro-1-fluoroethylene and 3,3,3-trifluoropropyne to test the validity of the theory. Through modeling one-dimensional slices of a traditional 2D plot, peaks in the indirectly measured frequency dimension were identified and classified and phenomenological selection rules were obtained.en_US
dc.language.isoenen_US
dc.publisherOhio State Universityen_US
dc.titleTWO-DIMENSIONAL CHIRPED-PULSE FOURIER TRANSFORM MICROWAVE SPECTROSCOPY: MODELING COHERENCE TRANSFERen_US
dc.typeArticleen_US
dc.typeImageen_US
dc.typePresentationen_US


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