dc.creator Wang, Fang en_US dc.creator Steimle, Timothy C. en_US dc.date.accessioned 2010-07-12T14:23:08Z dc.date.available 2010-07-12T14:23:08Z dc.date.issued 2010 en_US dc.identifier 2010-RG-14 en_US dc.identifier.uri http://hdl.handle.net/1811/46347 dc.description Author Institution: Department of Chemistry and Biochemistry, Arizona State University, Tempe,AZ 85287 en_US dc.description.abstract Copper hydroxide, CuOH, is one of the most thoroughly studied . {\textbf{144}} 286, 1990.} transition metal containing polyatomic molecules with the most recent investigation being the dispersed fluorescence and radiative lifetime study. . {\textbf{449}} 282, 2007.} The pure rotational spectrum was recorded and analyzed by Saito$^{\prime}$s group some time ago.. {\textbf{112}} 641, 2000.} Recently a high level {\textit{ab initio}} calculation predicted ground state permanent electric dipole moments, $\mu_{el}$, ranging in value from 5.52D to 3.98D depending upon methodology used to treat electron correlation. Here we report on the first molecular beam study of the B$^{1}$$A^{\prime\prime}-X^{1}A^{\prime } band. The spectrum was recorded field-free and in the presence of a static electric field of up to 4000 V/cm. The hyperfine splitting is observed and analyzed for the first time. The determined \mu_{el} values are used to evaluate the computational methodologies and are compared with those of other copper containing molecules. en_US dc.language.iso en en_US dc.publisher Ohio State University en_US dc.title OPTICAL STARK SPECTROSCOPY OF THE B^{1}$$A^{\prime\prime}$-X$^{1}$A$^{\prime }$ of CuOH en_US dc.type Article en_US dc.type Image en_US dc.type Presentation en_US
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