LONG RANGE PROTON-MIGRATION IN VUV PHOTOIONIZATION OF ACETONE CLUSTERS

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Creators:
Hanaue, Ken-Ichi
Matsuda, Yoshiyuki
Ohta, Keisuke
Mikami, Naohiko
Fujii, Asuka
Issue Date:
2010
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Publisher:
Ohio State University
Abstract:
Infrared spectroscopic investigations of neutral and cationic clusters of acetone reveals proton-migraion for keto-enol tautomerization in their ionization processes. In the reaction, the methyl proton of acetone is transferred to its carbonyl oxygen through the intracluster long range proton-migraion.
Description:
Author Institution: Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578,Japan
Type:
Article
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Presentation
Other Identifiers:
2010-RI-14
URI:
http://hdl.handle.net/1811/46179
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