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dc.creatorSun, M.en_US
dc.creatorClouthier, D. J.en_US
dc.creatorZiurys, L. M.en_US
dc.date.accessioned2010-07-12T14:00:49Z
dc.date.available2010-07-12T14:00:49Z
dc.date.issued2010en_US
dc.identifier2010-MH-06en_US
dc.identifier.urihttp://hdl.handle.net/1811/46155
dc.descriptionAuthor Institution: Department of Chemistry, Department of Astronomy, and Steward Observatory, University of Arizona, Tucson, AZ 85721; Department of Chemistry, University of Kentucky, Lexington, KY 40506; Department of Chemistry, Department of Astronomy, and Steward Observatory, University of Arizona, Tucson, AZ 85721en_US
dc.description.abstractThe microwave spectrum of AlCCH (X$^{1}\Sigma^+$) has been measured using Fourier transform microwave (FTMW) techniques in the frequency range of 9-40 GHz. This molecule was created in a supersonic expansion by the reaction of trimethyl aluminum, Al(CH$_3$)$_3$, and acetylene, C$_2$H$_2$, or methane, CH$_4$, diluted in argon carrier gas, using a pulsed nozzle coupled with a dc discharge. Spectra of Al$^{12}$C$^{13}$CH, Al$^{13}$C$^{12}$CH, Al$^{13}$C$^{13}$CH, Al$^{12}$C$^{12}$CD have also been recorded. From these data, rotational constants and Al and D hyperfine parameters have been determined, as well as the r$_m$$^{(1)}$ structure. AlCCH is a model system for heteroatom dicarbide species.en_US
dc.language.isoenen_US
dc.publisherOhio State Universityen_US
dc.titleFOURIER TRANSFORM MICROWAVE SPECTRUM OF AlCCH (X$^{1}\Sigma^+$) AND ITS $^{13}$C/D ISOTOPOLOGUESen_US
dc.typeArticleen_US


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