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dc.creatorBunting, Phil C.en_US
dc.creatorLear, Benjamin J.en_US
dc.creatorChisholm, Malcolm H.en_US
dc.date.accessioned2010-07-12T13:54:19Z
dc.date.available2010-07-12T13:54:19Z
dc.date.issued2010en_US
dc.identifier2010-MH-12en_US
dc.identifier.urihttp://hdl.handle.net/1811/46098
dc.descriptionAuthor Institution: The Ohio State University, Columbus, OH 43210en_US
dc.description.abstractThe synthesis of the metal-metal quadruple bond containing complex, (MM)(TiPB)$_2$(nic)$_2$, where M= Mo or W, TiPB= Triisopropylbenzoate, and nic= isonicotinate, is reported. This is invisioned as an inorganic analog of 4,4'-bipyridine, which is used to bridge two tris(pentafluro phenyl)borane units. The electronic and spectroscopic properties of both the parent compounds and the borane adducts are discussed. For both the molybdenum and tungsten complexes, addition of the borane significantly stabilizes the HOMO and, to a larger extent, the LUMO of the complexes. This results in a redshift in the metal to ligand charge transfer band for the neutral complexes and stabilizes the -1, mixed valence, state of the complexes.en_US
dc.language.isoenen_US
dc.publisherOhio State Universityen_US
dc.titleELECTRONIC AND SPECTROSCOPIC PROPERTIES OF A REDOX ACTIVE ANALOG OF 4,4'-BIPYRIDINE INCORPORATING A METAL-METAL QUADRUPLE BONDen_US
dc.typeArticleen_US
dc.typeImageen_US
dc.typePresentationen_US


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