Show simple item record

dc.contributor.advisorClark, Ted
dc.creatorPellegrini, Christine
dc.date.accessioned2010-05-17T14:44:23Z
dc.date.available2010-05-17T14:44:23Z
dc.date.issued2010-06
dc.identifier.urihttp://hdl.handle.net/1811/45372
dc.description.abstractQuantifying the concentration of arsenic in soil samples is important for many environmental chemistry investigations, including those characterizing heavy metal in urban settings and examining anthropogenic contributions. Although several approaches for quantifying arsenic in environmental samples have been reported, many of these are poorly suited for use in undergraduate teaching laboratories. The use of UV-Vis spectrophotometric methods are, for both logistical and pedagogical reasons, well-suited for inclusion in the chemistry curriculum. Within this investigation two UV-Vis spectrophotometric methods have been examined to ascertain their applicability for use at the undergraduate level. Criteria for inclusion in chemistry courses, such as time constraints, reproducibility, reagent stability, and dynamic range have been considered for a method employing a Leuco-malachite green dye (Revanasiddappa, 2007) or a method involving a Rhodamine B dye (Pillai, 2000). These two methods were examined in conjunction with two different soil digestion procedures for the analysis of soil samples collected from Columbus, OH. An investigation of the Leuco-malachite green method strongly suggests that it is ill-suited for the analysis of arsenic Columbus' soil due to interference from iron. The Rhodamine B method, in contrast, is less affected by iron or chromium interferrents and statistical analysis indicates good agreement between this method and X-ray fluorescence spectrophotometric analysis. However, poor precision in the Rhodamine B method, attributed in part to the digestion scheme, indicates that additional work is required before this method is included in undergraduate courses.en_US
dc.language.isoen_USen_US
dc.publisherThe Ohio State Universityen_US
dc.relation.ispartofseriesThe Ohio State University. Department of Chemistry Honors Theses; 2010en_US
dc.subjectArsenicen_US
dc.subjectUV/Visen_US
dc.subjectSoilen_US
dc.subjectSpectrophotometricen_US
dc.subjectRhodamineen_US
dc.subjectUndergraduateen_US
dc.titleInvestigating the Suitability of UV/Vis Spectrophotometric Methods for Analyzing Arsenic in Urban Soils for use in Undergraduate Laboratory Coursesen_US
dc.typeThesisen_US
dc.description.embargoNo embargoen_US


Files in this item

Thumbnail

Items in Knowledge Bank are protected by copyright, with all rights reserved, unless otherwise indicated.

This item appears in the following Collection(s)

Show simple item record