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dc.creatorWang, Hailingen_US
dc.creatorZhuang, Xiujuanen_US
dc.creatorSteimle, Timothy C.en_US
dc.date.accessioned2009-07-29T13:07:15Z
dc.date.available2009-07-29T13:07:15Z
dc.date.issued2009en_US
dc.identifier2009-RF-13en_US
dc.identifier.urihttp://hdl.handle.net/1811/38395
dc.descriptionTomonari,M.; Okuda, R.; Nagashima, U.; Tanaka, K.; Hirano, T.;\textit {J.~Chem.~Phys.en_US
dc.descriptionAuthor Institution: Department of Chemistry and Biochemistry, Arizona State University, Tempe,AZ 85287en_US
dc.description.abstractComparing the predicted and observed permanent electric dipole moments, $\mu$$_{el}$, for simple diatomic cobalt containing molecules is a means of testing computational methodologies used for modeling cobalt-catalyzed reactions. Here we report on the experimental determination of $\mu$$_{el}$ for CoH and CoF from the analysis of the Stark shifts in the (0,0) bands of the $A^{\prime}^{3}$$\Phi_{4}-X^{3}\Phi_{4}$ system of cobalt monohydride, CoH, and the $[18.8]^{3}$$\Phi_{4}-X^{3}\Phi_{4}$ system of cobalt monofluoride, CoF. In addition, the proton magnetic hyperfine interaction in CoH is analyzed. The relative values for $\mu$$_{el}$ are rationalized using a molecular orbital correlation diagram and with high-level \textit {ab initio} predictions\underline {\textbf{126}} 144307, 2007.}.en_US
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleTHE OPTICAL STARK SPECTRA OF CoF AND CoHen_US
dc.typeArticleen_US


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