dc.creator Gopal, Ram en_US dc.creator Ojha, K. S. en_US dc.creator Singh, S. C. en_US dc.date.accessioned 2009-07-29T12:58:23Z dc.date.available 2009-07-29T12:58:23Z dc.date.issued 2009 en_US dc.identifier 2009-FC-09 en_US dc.identifier.uri http://hdl.handle.net/1811/38285 dc.description Author Institution: Laboratory of Laser Spectroscopy and Nanomaterials; Department of Physics, University of Allahabad, ALLAHABAD - 211002, INDIA en_US dc.description.abstract Silicon containing molecules such as SiC, SiN and $Si_2$ are of astrophysical interest and their studies provide information about the construction and evolution of different interstellar bodies. The emission spectrum of silicon dimer is recorded in the region of 360-540 nm using laser ablation technique. A rotating silicon rod of high purity, placed in the ablation chamber under argon atmosphere of 0.1 torr pressure, is irradiated with focused output of 355 nm from pulsed Nd:YAG laser. The plasma thus produced by laser ablation is allowed to cool for 300 ns and emission from the cooled plasma is collected on the entrance slit of Spex TRIAX 320M monochomator with ICCD detector system. About 96 bands including 22 bands reported by previous workers are observed. All these bands are assigned into two new band systems H'-$D^3\Pi_u$, I-$X^3\Sigma_u^-$, and three already reported $H^3\Sigma_u^-$ - $X^3\Sigma_g^-$, $K^3\Pi_u^--X^3\Sigma_g^-$ and $L^3\Pi_g$-$D^3\Pi_u$ band systems of silicon dimer. Out of these 96 bands, 43 bands are assigned to two new band system H'-D and I-X while 33 bands including 17 bands reported by earlier workers in this region are assigned to H-X system of $Si_2$ molecule. In addition to these bands, two bands are assigned to K-X system while the three bands reported by $^aDouglas$ and $^bDubious$ and Leclercq are marked to L-D system. The detailed analyses of these systems are investigated in present work. The (0,0) band of H-X system is observed for the first time during this investigation. The molecular constants along with dissociation energies and internuclear distances are calculated from the observed spectra. \\ \\ $^aA. E. Douglas, Can. J. Phys. 33 (1955) 801-810$\\ $^bI.Dubois, H. Leclercq, Can.J.Phys 49 (1971) 3053-3054$ en_US dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title OPTICAL EMISSION STUDIES OF NEW BAND SYSTEM OF SILICON DIMER en_US dc.type Article en_US
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