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dc.creatorIshikawa, Harukien_US
dc.creatorEguchi, Toruen_US
dc.creatorFujihara, Akimasaen_US
dc.creatorYamada, Yujien_US
dc.creatorFuke, Kiyokazuen_US
dc.date.accessioned2009-07-29T12:56:00Z
dc.date.available2009-07-29T12:56:00Z
dc.date.issued2009en_US
dc.identifier2009-RA-11en_US
dc.identifier.urihttp://hdl.handle.net/1811/38252
dc.descriptionAuthor Institution: Department of Chemistry, Graduate School of Science, Kobe University, Nada-ku, Kobe 657-8501, Japanen_US
dc.description.abstractUntil now, a large number of studies on the microscopic solvation effect of metal ion have been carried out. However, a very small number of spectroscopic studies on the doubly-charged metal ions are reported compared with that on the singly-charged ion. Since doubly-charged metal ions are highly energetic, electron- or proton- transfer reactions with solvent molecules should compete with the stabilization by solvation. Thus, we have carried out infrared spectroscopy of the hydrated doubly-charged metal ions. \par In the present study, we used the electrospray ionization method to produce the hydrated doubly-charged metal ions. The ions mass-separated by the first quadrupole mass filter are irradiated by IR laser light and then fragment ions are detected by the second quadrupole mass analyzer. In the case of Mg$^{2+}$(H$_2$O)$_7$, a structure where one water molecule is hydrogen-bonded to the 6-coordinated Mg$^{2+}$ is indicated by the IR spectrum. IR spectra of other systems will be presented in the paper. \paren_US
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleINFRARED SPECTROSCOPY OF HYDRATED DOUBLY-CHARGED METAL IONS PRODUCED BY ELECTROSPRAY IONIZATIONen_US
dc.typeArticleen_US


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