Show simple item record

dc.creatorDoran, J. L.en_US
dc.creatorHon, B. J.en_US
dc.creatorLeopold, K. R.en_US
dc.date.accessioned2009-07-29T12:43:16Z
dc.date.available2009-07-29T12:43:16Z
dc.date.issued2009en_US
dc.identifier2009-RC-05en_US
dc.identifier.urihttp://hdl.handle.net/1811/38075
dc.descriptionAuthor Institution: Department of Chemistry, University of Minnesota, Minneapolis, MN 55455.en_US
dc.description.abstractRotational spectra of the NC$_{4}$H$_{4}$-CO$_{2}$ dimer and four isotopologs have been observed using Fourier transform microwave spectroscopy. Analysis of the rotational and quadrupole coupling constants will be presented. Preliminary structural analysis indicates the complex is planar; the CO$_{2}$ axis is perpendicular to the C$_{2}$ axis of pyridine with a C-N van der Waals bond length of 2.83 $\AA$. This complex provides the first step in the microsolvation of an organic solute using CO$_{2}$ as a solvent and therefore may be useful in understanding solute-solvent interactions in supercritical CO$_{2}$.en_US
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleA MICROWAVE INVESTIGATION OF THE CO$_2$-PYRIDINE VAN DER WAALS COMPLEXen_US
dc.typeArticleen_US


Files in this item

Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail

Items in Knowledge Bank are protected by copyright, with all rights reserved, unless otherwise indicated.

This item appears in the following Collection(s)

Show simple item record