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dc.creatorKang, Luen_US
dc.creatorSunahori, Fumie X.en_US
dc.creatorMinei, Andrea J.en_US
dc.creatorClouthier, Dennis J.en_US
dc.creatorNovick, Stewart E.en_US
dc.date.accessioned2008-07-15T13:39:22Z
dc.date.available2008-07-15T13:39:22Z
dc.date.issued2008en_US
dc.identifier2008-FC-09en_US
dc.identifier.urihttp://hdl.handle.net/1811/33372
dc.descriptionAuthor Institution: Department of Natural Sciences, Union College, Barbourville, KY 40906; Department of Chemistry, University of Kentucky, Lexington, KY 40506; Department of Chemistry, Wesleyan University, Middletown, CT 06459; Department of Chemistry, University of Kentucky, Lexington, KY 40506; Department of Chemistry, Wesleyan University, Middletown, CT 06459en_US
dc.description.abstractEight isotopologues each of HGeBr and of DGeBr have been studied in natural abundance by pulsed-jet Fourier transform microwave (FTMW) spectroscopy. Neon was passed over dry ice cooled H$_3$GeBr or D$_3$GeBr and introduced into the pulsed valve of the FTMW spectrometer. The HGeBr and the DGeBr were produced in-situ with a 1000 V discharge of the gas mixture immediately following the nozzle opening. Only \it a \rm -type transitions can be observed from 5 - 25 GHz; K$_a$ = 0 transitions for the HGeBr and K$_a$ = 0 and 1 transitions for the DGeBr isotopologues. The structure and bonding of the molecule will be discussed.en_US
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleMICROWAVE SPECTROSCOPY OF THE HEAVY-ATOM CARBENE ANALOG HGeBren_US
dc.typeArticleen_US


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