dc.creator Kisiel, Z. en_US dc.creator Bialkowska-Jaworska, E. en_US dc.creator Butler, R. A. H. en_US dc.creator Petkie, D. T. en_US dc.creator Helminger, P. en_US dc.creator De Lucia, F. C. en_US dc.date.accessioned 2008-07-15T13:38:46Z dc.date.available 2008-07-15T13:38:46Z dc.date.issued 2008 en_US dc.identifier 2008-FC-01 en_US dc.identifier.uri http://hdl.handle.net/1811/33364 dc.description R.A.H.Butler et al., J. Mol. Spectrosc. , bf 243R.A.H.Butler et al., J. Mol. Spectrosc. , bf 213 en_US dc.description Author Institution: Institute of Physics, Polish Academy of Sciences, Al. Lotnikow; 32/46, 02-668 Warszawa, Poland; Department of Physics, Pittsburg State University, Pittsburg, KS 66726; Department of Physics, Wright State University, Dayton, OH 45435; Department of Physics, University of South Alabama, Mobile, AL 36688; Department of Physics, The Ohio State University, Columbus; OH 43210 en_US dc.description.abstract The rotational spectrum of the stratospherically important ClONO$_2$ molecule has recently been subjected to an extended analysis,}, 1-9 (2007); {\bf 244}, 113-116 (2007).} which covered four states ranging from the ground state to the $\nu_5$/$\nu_6\nu_9$ dyad at $\approx$560 cm$^{-1}$. The analysis was based on a newly recorded broadband FASSST spectrum with an almost complete coverage of the 118-378 GHz region. \vspace{0.2cm} The remaining vibrational states below 560 cm$^{-1}$ are the three polyads associated with successively higher excitation of the $\nu_9$ mode. These are the ($2\nu_9/\nu_7$) dyad, the ($3\nu_9/\nu_7\nu_9$) dyad, and the ($4\nu_9/\nu_72\nu_9/2\nu_7$) triad. Rotational transitions in the triad were assigned for the first time and data sets for the two dyads were considerably improved over those obtained previously.}, 8-14 (2002); {\bf 220}, 150-152 (2003).} Transition frequencies in all three polyads, for both $^{35}$ClONO$_2$ and $^{37}$ClONO$_2$, were fitted to within experimental accuracy by using a new coupling scheme which accounted in a unified manner for the pertinent Fermi and Coriolis interactions. Various tests used to ensure that the 'true' solution has been reached are discussed. en_US dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title THE ROTATIONAL SPECTRUM OF CHLORINE NITRATE (ClONO$_2$) IN THE THREE LOWEST $n\nu_9$ POLYADS en_US dc.type Article en_US
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