Show simple item record

dc.creatorSedo, Galenen_US
dc.creatorCurtis, J.en_US
dc.creatorLeopold, K. R.en_US
dc.date.accessioned2008-01-12T13:53:27Z
dc.date.available2008-01-12T13:53:27Z
dc.date.issued2007en_US
dc.identifier2007-MG-03en_US
dc.identifier.urihttp://hdl.handle.net/1811/31402
dc.descriptionAuthor Institution: Department of Chemistry, University of Minnesota, 207 Pleasant St., SE,; Minneapolis,; MN 55455en_US
dc.description.abstractThe dipole moment of the sulfuric acid monomer, H$_2$SO$_4$, has been revisited using pulsed-nozzle Fourier transform microwave spectroscopy. A total of 91 Stark-shifted frequencies at a series of electric field strengths have been recorded for the known 1$_1$$_0$ $\leftarrow$ 0$_0$$_0$ transition. The total molecular dipole moment ($\mu$$_t$$_o$$_t$ = $\mu$$_c$) was found to be 2.9643(67) D, which is approximately 0.24 D greater than the best value previously available. An extensive computational investigation has also been performed in order to determine the effect of theoretical method and basis set on the calculated dipole moment. Calculations using the PW91 density functional perform exceedingly well and result in calculated values that converge to good agreement with the current experimental value.en_US
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleDIPOLE MOMENT OF THE SULFURIC ACID MONOMERen_US
dc.typearticleen_US


Files in this item

Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail
Thumbnail

Items in Knowledge Bank are protected by copyright, with all rights reserved, unless otherwise indicated.

This item appears in the following Collection(s)

Show simple item record