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dc.creatorMinei, Andrea J.en_US
dc.creatorNovick, Stewart E.en_US
dc.date.accessioned2008-01-12T13:48:21Z
dc.date.available2008-01-12T13:48:21Z
dc.date.issued2007en_US
dc.identifier2007-FB-04en_US
dc.identifier.urihttp://hdl.handle.net/1811/31340
dc.descriptionAuthor Institution: Department of Chemistry, Wesleyan University, Middletown, CT 06459en_US
dc.description.abstractRecently Afshari and coworkers} \textbf{XXX}, XXXX (2007); and A. R. W. McKellar, private communication.} reported on the detection of a new infrared band which was assigned to the "long-anticipated polar isomer of the OCS dimer". We report here the microwave confirmation of their results. The lowest energy, non-polar isomer of (OCS)$_2$ has long been known from IR spectroscopy, while the polar form has only been deduced from qualitative beam "refocussing" experiments. The higher energy, polar isomer of (OCS)$_2$ has been produced by high pressure expansion of dilute OCS in helium. A surprisingly strong microwave spectrum of C$_s$ (OCS)$_2$ has been observed and assigned. The structure of the dimer has been determined.en_US
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleMICROWAVE OBSERVATION OF THE 'RECENTLY FOUND' POLAR OCS DIMERen_US
dc.typearticleen_US


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