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dc.creatorAdam, A. G.en_US
dc.creatorDownie, Laura E.en_US
dc.creatorSlaney, M. E.en_US
dc.creatorBalfour, W. J.en_US
dc.creatorLi, Runhuaen_US
dc.date.accessioned2008-01-12T13:07:11Z
dc.date.available2008-01-12T13:07:11Z
dc.date.issued2006en_US
dc.identifier2006-MF-14en_US
dc.identifier.urihttp://hdl.handle.net/1811/30875
dc.descriptionAuthor Institution: Chemistry Department, and Centre for Lasers, and Atomic, and Molecular Sciences, University of New Brunswick, Fredericton, NB, E3B 6E2; Chemistry Department, University of Victoria, Victoria, BC, V8W 3P6en_US
dc.description.abstractHigh resolution laser spectra of RhP have been acquired in the visible region of the spectrum. The molecules were produced by laser ablation of a rhodium target rod followed by reaction with 2\% PH$_3$ seeded in He in a pulsed supersonic jet. At least three electronic transitions with extensive upper state vibrational progressions have been observed by laser-induced fluorescence between 420 nm and 510 nm. All the bands are degraded to longer wavelengths and have an R branch which rapidly forms a head and a more open P branch. First lines in the bands were seen allowing line assignments which are consistent with $^1$$\Sigma$ - $^1$$\Sigma$ transitions. Dispersed fluorescence from the bands give a ground state vibrational interval of approximately 507 cm$^{-1}$ plus also indicate the presence of low-lying electronic states at 2454 cm$^{-1}$ and 4691 cm$^{-1}$. Molecular constants for the excited and ground states will be presented.en_US
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleHIGH RESOLUTION LASER SPECTROSCOPY OF RHODIUM MONOPHOSPHIDEen_US
dc.typearticleen_US


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