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dc.creatorPeebles, Sean A.en_US
dc.creatorNewby, Josh J.en_US
dc.creatorSerafin, Michal M.en_US
dc.creatorPeebles, Rebecca A.en_US
dc.date.accessioned2008-01-11T21:47:54Z
dc.date.available2008-01-11T21:47:54Z
dc.date.issued2005en_US
dc.identifier2005-RH-12en_US
dc.identifier.urihttp://hdl.handle.net/1811/30470
dc.descriptionAuthor Institution: Department of Chemistry, Eastern Illinois University, 600 Lincoln Ave.,; Charleston, IL 61920 USAen_US
dc.description.abstractRotational spectra for five isotopomers of the dimethyl ether--acetylene complex have been measured by Fourier-transform microwave spectroscopy and the rotational constants and planar moments are consistent with a structure of effective $C_{2v}$ symmetry in which the HCCH lies along the $C_2$ axis of the dimethyl ether (DME). The C--H...O intermolecular distance is determined to be 2.08(3) \AA. Measurement of the dipole moment gives a value of $\mu_a = \mu_{total} = 1.79(4)$D, also consistent with a $C_{2v}$ symmetry geometry. \vspace{1em} {\it Ab initio} calculations at the MP2/6-311++G(2d,2p) level reveal a very flat potential energy surface around the $C_{2v}$ geometry; basis set superposition error and zero point energy corrections are found to be crucial in predicting the correct order of stabilities of the minima located on the potential energy surface. Less than 24 cm$^{-1}$ separates the structure in which the HCCH is coordinated to the lone pair of electrons on the DME from the structure with the HCCH lying along the $C_2$ axis of the DME. The structure and binding of the DME--HCCH complex will be described and compared to similar complexes.en_US
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleEFFECTIVE $C_{2v}$ SYMMETRY IN THE DIMETHYL ETHER--ACETYLENE DIMERen_US
dc.typearticleen_US


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