dc.creator Peebles, Sean A. en_US dc.creator Newby, Josh J. en_US dc.creator Serafin, Michal M. en_US dc.creator Peebles, Rebecca A. en_US dc.date.accessioned 2008-01-11T21:47:54Z dc.date.available 2008-01-11T21:47:54Z dc.date.issued 2005 en_US dc.identifier 2005-RH-12 en_US dc.identifier.uri http://hdl.handle.net/1811/30470 dc.description Author Institution: Department of Chemistry, Eastern Illinois University, 600 Lincoln Ave.,; Charleston, IL 61920 USA en_US dc.description.abstract Rotational spectra for five isotopomers of the dimethyl ether--acetylene complex have been measured by Fourier-transform microwave spectroscopy and the rotational constants and planar moments are consistent with a structure of effective $C_{2v}$ symmetry in which the HCCH lies along the $C_2$ axis of the dimethyl ether (DME). The C--H...O intermolecular distance is determined to be 2.08(3) \AA. Measurement of the dipole moment gives a value of $\mu_a = \mu_{total} = 1.79(4)$D, also consistent with a $C_{2v}$ symmetry geometry. \vspace{1em} {\it Ab initio} calculations at the MP2/6-311++G(2d,2p) level reveal a very flat potential energy surface around the $C_{2v}$ geometry; basis set superposition error and zero point energy corrections are found to be crucial in predicting the correct order of stabilities of the minima located on the potential energy surface. Less than 24 cm$^{-1}$ separates the structure in which the HCCH is coordinated to the lone pair of electrons on the DME from the structure with the HCCH lying along the $C_2$ axis of the DME. The structure and binding of the DME--HCCH complex will be described and compared to similar complexes. en_US dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title EFFECTIVE $C_{2v}$ SYMMETRY IN THE DIMETHYL ETHER--ACETYLENE DIMER en_US dc.type article en_US
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