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dc.creatorLin, Weien_US
dc.creatorMinei, Andrea J.en_US
dc.creatorBrooks, Andrew H.en_US
dc.creatorPringle, Wallace C.en_US
dc.creatorNovick, Stewart E.en_US
dc.date.accessioned2008-01-11T21:47:43Z
dc.date.available2008-01-11T21:47:43Z
dc.date.issued2005en_US
dc.identifier2005-RH-09en_US
dc.identifier.urihttp://hdl.handle.net/1811/30467
dc.descriptionAuthor Institution: Department of Chemistry, Wesleyan University, Middletown, CT 06459en_US
dc.description.abstractRotational spectra of the neon cyclopentanone van der Waals complex were studied using a pulsed-jet Fabry-Perot Fourier transform microwave spectrometer. Spectra of the normal isotopomer along with those of five $^{13}$C, the $^{18}$O, and the $^{22}$Ne substituted isotopomers were assigned in the frequency region of 6-23 GHz. The asymmetry of the neon location within the complex allows the observation of \it a\rm, \it b\rm, and \it c\rm -type transitions. The rotational constants and centrifugal distortion constants for the parent isotopomer were determined to be \it A \rm = 2728.8119(7), \it B \rm = 1736.5880(5), and \it C \rm = 1440.4682(5) MHz; and $\Delta_J$ = 15.051(7), $\Delta_{JK}$ = -13.96(4), $\Delta_K$ = 49.97(5), $\delta_J$ = 3.603(3), and $\delta_K$ = 6.55(8) kHz. The coordinates of the neon in the principal axis system of C$_5$H$_8$O are \it a \rm = 0.91, \it b \rm = 0.78, and \it c \rm = 3.26 \AA, where the carbonyl bond lies along the \it a\rm -axis and the oxygen position is \it a \rm = 2.05 \AA. Comparisons between the bonding and wide amplitude motions of the rare gases in the neon verses the argon cyclopentanone complexes will be discussed.en_US
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleDETERMINATION OF THE STRUCTURE OF NEON CYCLOPENTANONEen_US
dc.typearticleen_US


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