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dc.creatorBorho, N.en_US
dc.creatorSuhm, M. A.en_US
dc.date.accessioned2008-01-11T21:36:15Z
dc.date.available2008-01-11T21:36:15Z
dc.date.issued2005en_US
dc.identifier2005-FC-10en_US
dc.identifier.urihttp://hdl.handle.net/1811/30278
dc.description{T. Haber, U. Schmitt and M. A. Suhm, Phys. Chem. Chem. Phys. 1, 5573 (1999).{C. A. Rice, N. Borho and M. A. Suhm, Z. Phys. Chem, 219, 1, (2005).{N. Borho and M. A. Suhm, Org. Biomol. Chem. 1, 4351 (2003).en_US
dc.descriptionAuthor Institution: Department of Chemistry, University of Alberta, Edmonton,; Canada T6G 2G2; Institut fur Physikalische Chemie,; Universitat Gottingen, D-37077 Gottingen, Germanyen_US
dc.description.abstractChiral Recognition was investigated via direct FTIR-spectroscopy in a supersonic expansion. Ragout-jet} and also Filet-jet} FTIR-spectroscopy are well-suited to distinguish between enantiopure and racemic molecule/rare gas expansions. The $\alpha$-hydroxyester methyl lactate shows an outstanding chiral recognition effect associated with specific self-aggregation }. The infrared $\nu_{OH}$ spectra will be analysed with the help of pressure dependence studies, argon coating and difference techniques. Additionally, a systematic study of analogues such as ethyl-, isopropyl- and \textit{tert}-butyl lactate ester, methyl glycolate, methyl $\alpha$-hydroxyisobutyrate, $\alpha$-hydroxyketones and mixed methyl lactate-methanol clusters will be presented. This study allows us to draw conclusions about the role of different functional groups involved in the intermolecular interactions of methyl lactate clusters. Preliminary quantum mechanical calculations reveal possible structures of methyl lactate aggregates.en_US
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleCHIRAL RECOGNITION IN MOLECULAR CLUSTERSen_US
dc.typearticleen_US


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