Show simple item record

dc.creatorLawrence, W. G.en_US
dc.creatorLin, H.- S.en_US
dc.creatorGoedderz, K. H.en_US
dc.creatorHeaven, M. C.en_US
dc.descriptionWork supported by NSF under grant CHE-9320094en_US
dc.descriptionAuthor Institution: Emory University, Emory University, Atlanta GA 30322en_US
dc.description.abstractThe photoinduced reaction of HCl dimers upon 193 nm excitation is demonstrated by the formation of $Cl_{2}$ monomers. The products were detected by laser induced fluorescence from the $Cl_{2}A^{\prime} \rightarrow X$ transition. Two mechanisms for the formation of $Cl_{2}$ are considered. The first requires two sequential H atom cage exit steps. Alternatively, a single step mechanism for the caged reaction is considered. A statistical model for deriving the rate constant of the caged reaction will be presented.en_US
dc.format.extent35037 bytes
dc.publisherOhio State Universityen_US
dc.titlePhotoinduced Reaction Pathways of HCl Dimers in an Argon Matrixen_US

Files in this item


Items in Knowledge Bank are protected by copyright, with all rights reserved, unless otherwise indicated.

This item appears in the following Collection(s)

Show simple item record