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dc.creatorIrikura, K. K.en_US
dc.creatorJacox, Marilyn E.en_US
dc.creatorThompson, Warren E.en_US
dc.date.accessioned2007-11-20T17:17:01Z
dc.date.available2007-11-20T17:17:01Z
dc.date.issued1995en_US
dc.identifier1995-FE-01en_US
dc.identifier.urihttp://hdl.handle.net/1811/29946
dc.description1. H. Takeo and R. F. Curl, J. Chem. Phys. 56, 4314 (1972).en_US
dc.descriptionAuthor Institution: National Institute of Standards and Technology, Gaithersburg, MD 20899.; National Institute of Standards and Technology, Gaithersburg, MD 20899.en_US
dc.description.abstractAlthough the interaction of $BF_{3}$ with traces of water in the vacuum system has been $shown^{1}$ to result in the formation of sufficient $BF_{2}OH$ for determination of its microwave spectrum and structure, the infrared spectrum of that molecule has not previously been reported. Prominent impurity absorptions in the infrared spectra of solid $Ne:BF_{3}$ samples at 5 K can be assigned to $BF_{2}OH$, formed by the reaction of $BF_{3}$ with water adsorbed on the walls of the deposition system. This assignment is supported by the results of experiments in which the sampling system is exposed to water enriched in deuterium and/or in oxygen-18 before the introduction of the $Ne:BF_{3}$ mixture and by ab initio calculations of the positions of the vibrational fundamentals of the various isotopically substituted $BF_{2}OH$ species. The detailed vibrational assignment and normal coordinate analysis for $BF_{2}OH$ will be presented.en_US
dc.format.extent56724 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleTHE VIBRATIONAL SPECTRUM OF $BF_{2}OH$ TRAPPED IN SOLID NEONen_US
dc.typearticleen_US


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